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Metal Hydrides Form Halogen Bonds: Measurement of Energetics of Binding
[Image: see text] The formation of halogen bonds from iodopentafluorobenzene and 1-iodoperfluorohexane to a series of bis(η(5)-cyclopentadienyl)metal hydrides (Cp(2)TaH(3), 1; Cp(2)MH(2), M = Mo, 2, M = W, 3; Cp(2)ReH, 4; Cp(2)Ta(H)CO, 5; Cp = η(5)-cyclopentadienyl) is demonstrated by (1)H NMR spect...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2013
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3928989/ https://www.ncbi.nlm.nih.gov/pubmed/24380577 http://dx.doi.org/10.1021/ja4121499 |