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Turnover-Dependent Inactivation of the Nitrogenase MoFe-Protein at High pH
[Image: see text] Proton uptake accompanies the reduction of all known substrates by nitrogenase. As a consequence, a higher pH should limit the availability of protons as a substrate essential for turnover, thereby increasing the proportion of more highly reduced forms of the enzyme for further stu...
Autores principales: | Yang, Kun-Yun, Haynes, Chad A., Spatzal, Thomas, Rees, Douglas C., Howard, James B. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2013
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3932303/ https://www.ncbi.nlm.nih.gov/pubmed/24392967 http://dx.doi.org/10.1021/bi4014769 |
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