Cargando…

Improved reversibility in lithium-oxygen battery: Understanding elementary reactions and surface charge engineering of metal alloy catalyst

Most Li-O(2) batteries suffer from sluggish kinetics during oxygen evolution reactions (OERs). To overcome this drawback, we take the lesson from other catalysis researches that showed improved catalytic activities by employing metal alloy catalysts. Such research effort has led us to find Pt(3)Co n...

Descripción completa

Detalles Bibliográficos
Autores principales: Kim, Byung Gon, Kim, Hyung-Jin, Back, Seoin, Nam, Kwan Woo, Jung, Yousung, Han, Young-Kyu, Choi, Jang Wook
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3936231/
https://www.ncbi.nlm.nih.gov/pubmed/24573326
http://dx.doi.org/10.1038/srep04225
Descripción
Sumario:Most Li-O(2) batteries suffer from sluggish kinetics during oxygen evolution reactions (OERs). To overcome this drawback, we take the lesson from other catalysis researches that showed improved catalytic activities by employing metal alloy catalysts. Such research effort has led us to find Pt(3)Co nanoparticles as an effective OER catalyst in Li-O(2) batteries. The superior catalytic activity was reflected in the substantially decreased overpotentials and improved cycling/rate performance compared to those of other catalysts. Density functional theory calculations suggested that the low OER overpotentials are associated with the reduced adsorption strength of LiO(2) on the outermost Pt catalytic sites. Also, the alloy catalyst generates amorphous Li(2)O(2) conformally coated around the catalyst and thus facilitates easier decomposition and higher reversibility. This investigation conveys an important message that understanding elementary reactions and surface charge engineering of air-catalysts are one of the most effective approaches in resolving the chronic sluggish charging kinetics in Li-O(2) batteries.