High-Pressure Synthesis and Characterization of the Actinide Borate Phosphate U(2)[BO(4)][PO(4)]

A new actinide borate phosphate, U(2)[BO(4)][PO(4)], was synthesized in a Walker-type multianvil apparatus at 12.5 GPa and 1000 °C. The crystal structure was determined from single-crystal X-ray diffraction data collected at room temperature. U(2)[BO(4)][PO(4)] crystallizes in the monoclinic space g...

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Autores principales: Hinteregger, Ernst, Wurst, Klaus, Perfler, Lukas, Kraus, Florian, Huppertz, Hubert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2013
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3939824/
https://www.ncbi.nlm.nih.gov/pubmed/24611029
http://dx.doi.org/10.1002/ejic.201300662
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author Hinteregger, Ernst
Wurst, Klaus
Perfler, Lukas
Kraus, Florian
Huppertz, Hubert
author_facet Hinteregger, Ernst
Wurst, Klaus
Perfler, Lukas
Kraus, Florian
Huppertz, Hubert
author_sort Hinteregger, Ernst
collection PubMed
description A new actinide borate phosphate, U(2)[BO(4)][PO(4)], was synthesized in a Walker-type multianvil apparatus at 12.5 GPa and 1000 °C. The crystal structure was determined from single-crystal X-ray diffraction data collected at room temperature. U(2)[BO(4)][PO(4)] crystallizes in the monoclinic space group P2(1)/c with four formula units per unit cell and the lattice parameters a = 854.6(2), b = 775.3(2), c = 816.3(2) pm, and β = 102.52(3)°. The structure consists of double layers of linked uranium–oxygen polyhedra parallel to [100]. The borate tetrahedra are located between the uranium–oxygen layers inside the double layer. The phosphate groups link the double layers.
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spelling pubmed-39398242014-03-06 High-Pressure Synthesis and Characterization of the Actinide Borate Phosphate U(2)[BO(4)][PO(4)] Hinteregger, Ernst Wurst, Klaus Perfler, Lukas Kraus, Florian Huppertz, Hubert Eur J Inorg Chem Full Papers A new actinide borate phosphate, U(2)[BO(4)][PO(4)], was synthesized in a Walker-type multianvil apparatus at 12.5 GPa and 1000 °C. The crystal structure was determined from single-crystal X-ray diffraction data collected at room temperature. U(2)[BO(4)][PO(4)] crystallizes in the monoclinic space group P2(1)/c with four formula units per unit cell and the lattice parameters a = 854.6(2), b = 775.3(2), c = 816.3(2) pm, and β = 102.52(3)°. The structure consists of double layers of linked uranium–oxygen polyhedra parallel to [100]. The borate tetrahedra are located between the uranium–oxygen layers inside the double layer. The phosphate groups link the double layers. WILEY-VCH Verlag 2013-10-14 2013-09-10 /pmc/articles/PMC3939824/ /pubmed/24611029 http://dx.doi.org/10.1002/ejic.201300662 Text en © 2013 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution-NonCommercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes. http://creativecommons.org/licenses/by/2.5/ Re-use of this article is permitted in accordance with the Creative Commons Deed, Attribution 2.5, which does not permit commercial exploitation.
spellingShingle Full Papers
Hinteregger, Ernst
Wurst, Klaus
Perfler, Lukas
Kraus, Florian
Huppertz, Hubert
High-Pressure Synthesis and Characterization of the Actinide Borate Phosphate U(2)[BO(4)][PO(4)]
title High-Pressure Synthesis and Characterization of the Actinide Borate Phosphate U(2)[BO(4)][PO(4)]
title_full High-Pressure Synthesis and Characterization of the Actinide Borate Phosphate U(2)[BO(4)][PO(4)]
title_fullStr High-Pressure Synthesis and Characterization of the Actinide Borate Phosphate U(2)[BO(4)][PO(4)]
title_full_unstemmed High-Pressure Synthesis and Characterization of the Actinide Borate Phosphate U(2)[BO(4)][PO(4)]
title_short High-Pressure Synthesis and Characterization of the Actinide Borate Phosphate U(2)[BO(4)][PO(4)]
title_sort high-pressure synthesis and characterization of the actinide borate phosphate u(2)[bo(4)][po(4)]
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3939824/
https://www.ncbi.nlm.nih.gov/pubmed/24611029
http://dx.doi.org/10.1002/ejic.201300662
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