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A Diels–Alder super diene breaking benzene into C(2)H(2) and C(4)H(4) units

Cyclic polyene with six carbon atoms (benzene) is very stable, whereas cyclic polyene with four carbon atoms (cyclobutadiene) is extremely unstable. The electron-withdrawing pentafluorophenyl group of a substituted cyclobutadiene lowers the energy of the lowest unoccupied molecular orbital, greatly...

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Detalles Bibliográficos
Autores principales:	Inagaki, Yusuke, Nakamoto, Masaaki, Sekiguchi, Akira
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Pub. Group 2014
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3941017/ https://www.ncbi.nlm.nih.gov/pubmed/24398593 http://dx.doi.org/10.1038/ncomms4018

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