Convergent synthesis of a tetrasaccharide repeating unit of the O-specific polysaccharide from the cell wall lipopolysaccharide of Azospirillum brasilense strain Sp7

A straightforward convergent synthesis has been carried out for the tetrasaccharide repeating unit of the O-specific cell wall lipopolysaccharide of the strain Sp7 of Azospirillum brasilense. The target tetrasaccharide has been synthesized from suitably protected monosaccharide intermediates in 42%...

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Detalles Bibliográficos
Autores principales: Mandal, Pintu Kumar, Dhara, Debashis, Misra, Anup Kumar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3943683/
https://www.ncbi.nlm.nih.gov/pubmed/24605150
http://dx.doi.org/10.3762/bjoc.10.26
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author Mandal, Pintu Kumar
Dhara, Debashis
Misra, Anup Kumar
author_facet Mandal, Pintu Kumar
Dhara, Debashis
Misra, Anup Kumar
author_sort Mandal, Pintu Kumar
collection PubMed
description A straightforward convergent synthesis has been carried out for the tetrasaccharide repeating unit of the O-specific cell wall lipopolysaccharide of the strain Sp7 of Azospirillum brasilense. The target tetrasaccharide has been synthesized from suitably protected monosaccharide intermediates in 42% overall yield in seven steps by using a [2 + 2] block glycosylation approach.
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spelling pubmed-39436832014-03-06 Convergent synthesis of a tetrasaccharide repeating unit of the O-specific polysaccharide from the cell wall lipopolysaccharide of Azospirillum brasilense strain Sp7 Mandal, Pintu Kumar Dhara, Debashis Misra, Anup Kumar Beilstein J Org Chem Full Research Paper A straightforward convergent synthesis has been carried out for the tetrasaccharide repeating unit of the O-specific cell wall lipopolysaccharide of the strain Sp7 of Azospirillum brasilense. The target tetrasaccharide has been synthesized from suitably protected monosaccharide intermediates in 42% overall yield in seven steps by using a [2 + 2] block glycosylation approach. Beilstein-Institut 2014-01-29 /pmc/articles/PMC3943683/ /pubmed/24605150 http://dx.doi.org/10.3762/bjoc.10.26 Text en Copyright © 2014, Mandal et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Mandal, Pintu Kumar
Dhara, Debashis
Misra, Anup Kumar
Convergent synthesis of a tetrasaccharide repeating unit of the O-specific polysaccharide from the cell wall lipopolysaccharide of Azospirillum brasilense strain Sp7
title Convergent synthesis of a tetrasaccharide repeating unit of the O-specific polysaccharide from the cell wall lipopolysaccharide of Azospirillum brasilense strain Sp7
title_full Convergent synthesis of a tetrasaccharide repeating unit of the O-specific polysaccharide from the cell wall lipopolysaccharide of Azospirillum brasilense strain Sp7
title_fullStr Convergent synthesis of a tetrasaccharide repeating unit of the O-specific polysaccharide from the cell wall lipopolysaccharide of Azospirillum brasilense strain Sp7
title_full_unstemmed Convergent synthesis of a tetrasaccharide repeating unit of the O-specific polysaccharide from the cell wall lipopolysaccharide of Azospirillum brasilense strain Sp7
title_short Convergent synthesis of a tetrasaccharide repeating unit of the O-specific polysaccharide from the cell wall lipopolysaccharide of Azospirillum brasilense strain Sp7
title_sort convergent synthesis of a tetrasaccharide repeating unit of the o-specific polysaccharide from the cell wall lipopolysaccharide of azospirillum brasilense strain sp7
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3943683/
https://www.ncbi.nlm.nih.gov/pubmed/24605150
http://dx.doi.org/10.3762/bjoc.10.26
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