Decandrinin, an unprecedented C(9)-spiro-fused 7,8-seco-ent-abietane from the Godavari mangrove Ceriops decandra

Decandrinin (1), an unprecedented C(9)-spiro-fused 7,8-seco-ent-abietane, was obtained from the bark of an Indian mangrove, Ceriops decandra, collected in the estuary of Godavari, Andhra Pradesh. The constitution and the relative configuration of 1 were determined by HRMS (ESI) and extensive NMR inv...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Hui, Li, Min-Yi, Katele, Félix Zongwe, Satyanandamurty, Tirumani, Wu, Jun, Bringmann, Gerhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3943825/
https://www.ncbi.nlm.nih.gov/pubmed/24605147
http://dx.doi.org/10.3762/bjoc.10.23
_version_ 1782306306896429056
author Wang, Hui
Li, Min-Yi
Katele, Félix Zongwe
Satyanandamurty, Tirumani
Wu, Jun
Bringmann, Gerhard
author_facet Wang, Hui
Li, Min-Yi
Katele, Félix Zongwe
Satyanandamurty, Tirumani
Wu, Jun
Bringmann, Gerhard
author_sort Wang, Hui
collection PubMed
description Decandrinin (1), an unprecedented C(9)-spiro-fused 7,8-seco-ent-abietane, was obtained from the bark of an Indian mangrove, Ceriops decandra, collected in the estuary of Godavari, Andhra Pradesh. The constitution and the relative configuration of 1 were determined by HRMS (ESI) and extensive NMR investigations, and the absolute configuration by circular dichroism (CD) and optical-rotatory dispersion (ORD) spectroscopy in combination with quantum-chemical calculations. Decandrinin is the first 7,8-seco-ent-abietane.
format Online
Article
Text
id pubmed-3943825
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher Beilstein-Institut
record_format MEDLINE/PubMed
spelling pubmed-39438252014-03-06 Decandrinin, an unprecedented C(9)-spiro-fused 7,8-seco-ent-abietane from the Godavari mangrove Ceriops decandra Wang, Hui Li, Min-Yi Katele, Félix Zongwe Satyanandamurty, Tirumani Wu, Jun Bringmann, Gerhard Beilstein J Org Chem Full Research Paper Decandrinin (1), an unprecedented C(9)-spiro-fused 7,8-seco-ent-abietane, was obtained from the bark of an Indian mangrove, Ceriops decandra, collected in the estuary of Godavari, Andhra Pradesh. The constitution and the relative configuration of 1 were determined by HRMS (ESI) and extensive NMR investigations, and the absolute configuration by circular dichroism (CD) and optical-rotatory dispersion (ORD) spectroscopy in combination with quantum-chemical calculations. Decandrinin is the first 7,8-seco-ent-abietane. Beilstein-Institut 2014-01-27 /pmc/articles/PMC3943825/ /pubmed/24605147 http://dx.doi.org/10.3762/bjoc.10.23 Text en Copyright © 2014, Wang et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Wang, Hui
Li, Min-Yi
Katele, Félix Zongwe
Satyanandamurty, Tirumani
Wu, Jun
Bringmann, Gerhard
Decandrinin, an unprecedented C(9)-spiro-fused 7,8-seco-ent-abietane from the Godavari mangrove Ceriops decandra
title Decandrinin, an unprecedented C(9)-spiro-fused 7,8-seco-ent-abietane from the Godavari mangrove Ceriops decandra
title_full Decandrinin, an unprecedented C(9)-spiro-fused 7,8-seco-ent-abietane from the Godavari mangrove Ceriops decandra
title_fullStr Decandrinin, an unprecedented C(9)-spiro-fused 7,8-seco-ent-abietane from the Godavari mangrove Ceriops decandra
title_full_unstemmed Decandrinin, an unprecedented C(9)-spiro-fused 7,8-seco-ent-abietane from the Godavari mangrove Ceriops decandra
title_short Decandrinin, an unprecedented C(9)-spiro-fused 7,8-seco-ent-abietane from the Godavari mangrove Ceriops decandra
title_sort decandrinin, an unprecedented c(9)-spiro-fused 7,8-seco-ent-abietane from the godavari mangrove ceriops decandra
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3943825/
https://www.ncbi.nlm.nih.gov/pubmed/24605147
http://dx.doi.org/10.3762/bjoc.10.23
work_keys_str_mv AT wanghui decandrininanunprecedentedc9spirofused78secoentabietanefromthegodavarimangroveceriopsdecandra
AT liminyi decandrininanunprecedentedc9spirofused78secoentabietanefromthegodavarimangroveceriopsdecandra
AT katelefelixzongwe decandrininanunprecedentedc9spirofused78secoentabietanefromthegodavarimangroveceriopsdecandra
AT satyanandamurtytirumani decandrininanunprecedentedc9spirofused78secoentabietanefromthegodavarimangroveceriopsdecandra
AT wujun decandrininanunprecedentedc9spirofused78secoentabietanefromthegodavarimangroveceriopsdecandra
AT bringmanngerhard decandrininanunprecedentedc9spirofused78secoentabietanefromthegodavarimangroveceriopsdecandra

Ejemplares similares