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Recent applications of the divinylcyclopropane–cycloheptadiene rearrangement in organic synthesis

This review summarizes the application of the divinylcyclopropane–cycloheptadiene rearrangement in synthetic organic chemistry. A brief overview of the new mechanistic insights concerning the title reaction is provided as well as a condensed account on the biological relevance of the topic. Heteroat...

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Detalles Bibliográficos
Autores principales: Krüger, Sebastian, Gaich, Tanja
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3943923/
https://www.ncbi.nlm.nih.gov/pubmed/24605138
http://dx.doi.org/10.3762/bjoc.10.14
Descripción
Sumario:This review summarizes the application of the divinylcyclopropane–cycloheptadiene rearrangement in synthetic organic chemistry. A brief overview of the new mechanistic insights concerning the title reaction is provided as well as a condensed account on the biological relevance of the topic. Heteroatom variants of this rearrangement are covered briefly.