Cargando…
H(2)O(2)-dependent substrate oxidation by an engineered diiron site in a bacterial hemerythrin
The O(2)-binding carboxylate-bridged diiron site in DcrH-Hr was engineered in an effort to perform the H(2)O(2)-dependent oxidation of external substrates. A His residue was introduced near the diiron site in place of a conserved residue, Ile119. The I119H variant promotes the oxidation of guaiacol...
| Autores principales: | , , , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2014
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3947700/ https://www.ncbi.nlm.nih.gov/pubmed/24400317 http://dx.doi.org/10.1039/c3cc48108e |