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Mechanical Property and Structure of Covalent Functionalised Graphene/Epoxy Nanocomposites

Thermally reduced graphene nanoplatelets were covalently functionalised via Bingel reaction to improve their dispersion and interfacial bonding with an epoxy resin. Functionalised graphene were characterized by microscopic, thermal and spectroscopic techniques. Thermal analysis of functionalised gra...

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Detalles Bibliográficos
Autores principales: Naebe, Minoo, Wang, Jing, Amini, Abbas, Khayyam, Hamid, Hameed, Nishar, Li, Lu Hua, Chen, Ying, Fox, Bronwyn
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3953726/
https://www.ncbi.nlm.nih.gov/pubmed/24625497
http://dx.doi.org/10.1038/srep04375
Descripción
Sumario:Thermally reduced graphene nanoplatelets were covalently functionalised via Bingel reaction to improve their dispersion and interfacial bonding with an epoxy resin. Functionalised graphene were characterized by microscopic, thermal and spectroscopic techniques. Thermal analysis of functionalised graphene revealed a significantly higher thermal stability compared to graphene oxide. Inclusion of only 0.1 wt% of functionalised graphene in an epoxy resin showed 22% increase in flexural strength and 18% improvement in storage modulus. The improved mechanical properties of nanocomposites is due to the uniform dispersion of functionalised graphene and strong interfacial bonding between modified graphene and epoxy resin as confirmed by microscopy observations.