A Broadly Applicable NHC–Cu-Catalyzed Approach for Efficient, Site-, and Enantioselective Coupling of Readily Accessible (Pinacolato)alkenylboron Compounds to Allylic Phosphates and Applications to Natural Product Synthesis

[Image: see text] A set of protocols for catalytic enantioselective allylic substitution (EAS) reactions that allow for additions of alkenyl units to readily accessible allylic electrophiles is disclosed. Transformations afford 1,4-dienes that contain a tertiary carbon stereogenic site and are promo...

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Detalles Bibliográficos
Autores principales: Gao, Fang, Carr, James L., Hoveyda, Amir H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3954459/
https://www.ncbi.nlm.nih.gov/pubmed/24467274
http://dx.doi.org/10.1021/ja4126565

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3954459/
https://www.ncbi.nlm.nih.gov/pubmed/24467274
http://dx.doi.org/10.1021/ja4126565

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