Cationic Cyclizations and Rearrangements Promoted by a Heterogeneous Gold Catalyst

[Image: see text] A heterogeneous gold catalyst with remarkable activity for promoting the electrophilic reactions of aryl vinyl ketones and aryl dienyl ketones is described. The catalyst is easy to prepare, is robust, and can be recycled. Low loadings are effective for different types of cationic r...

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Detalles Bibliográficos
Autores principales: Vaidya, Tulaza, Cheng, Ryan, Carlsen, Peter N., Frontier, Alison J., Eisenberg, Richard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3969096/
https://www.ncbi.nlm.nih.gov/pubmed/24432741
http://dx.doi.org/10.1021/ol403542k
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author Vaidya, Tulaza
Cheng, Ryan
Carlsen, Peter N.
Frontier, Alison J.
Eisenberg, Richard
author_facet Vaidya, Tulaza
Cheng, Ryan
Carlsen, Peter N.
Frontier, Alison J.
Eisenberg, Richard
author_sort Vaidya, Tulaza
collection PubMed
description [Image: see text] A heterogeneous gold catalyst with remarkable activity for promoting the electrophilic reactions of aryl vinyl ketones and aryl dienyl ketones is described. The catalyst is easy to prepare, is robust, and can be recycled. Low loadings are effective for different types of cationic reactions, including Nazarov cyclizations, lactonizations, and [1,2] shifts.
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spelling pubmed-39690962015-01-16 Cationic Cyclizations and Rearrangements Promoted by a Heterogeneous Gold Catalyst Vaidya, Tulaza Cheng, Ryan Carlsen, Peter N. Frontier, Alison J. Eisenberg, Richard Org Lett [Image: see text] A heterogeneous gold catalyst with remarkable activity for promoting the electrophilic reactions of aryl vinyl ketones and aryl dienyl ketones is described. The catalyst is easy to prepare, is robust, and can be recycled. Low loadings are effective for different types of cationic reactions, including Nazarov cyclizations, lactonizations, and [1,2] shifts. American Chemical Society 2014-01-16 2014-02-07 /pmc/articles/PMC3969096/ /pubmed/24432741 http://dx.doi.org/10.1021/ol403542k Text en Copyright © 2014 American Chemical Society
spellingShingle Vaidya, Tulaza
Cheng, Ryan
Carlsen, Peter N.
Frontier, Alison J.
Eisenberg, Richard
Cationic Cyclizations and Rearrangements Promoted by a Heterogeneous Gold Catalyst
title Cationic Cyclizations and Rearrangements Promoted by a Heterogeneous Gold Catalyst
title_full Cationic Cyclizations and Rearrangements Promoted by a Heterogeneous Gold Catalyst
title_fullStr Cationic Cyclizations and Rearrangements Promoted by a Heterogeneous Gold Catalyst
title_full_unstemmed Cationic Cyclizations and Rearrangements Promoted by a Heterogeneous Gold Catalyst
title_short Cationic Cyclizations and Rearrangements Promoted by a Heterogeneous Gold Catalyst
title_sort cationic cyclizations and rearrangements promoted by a heterogeneous gold catalyst
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3969096/
https://www.ncbi.nlm.nih.gov/pubmed/24432741
http://dx.doi.org/10.1021/ol403542k
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AT carlsenpetern cationiccyclizationsandrearrangementspromotedbyaheterogeneousgoldcatalyst
AT frontieralisonj cationiccyclizationsandrearrangementspromotedbyaheterogeneousgoldcatalyst
AT eisenbergrichard cationiccyclizationsandrearrangementspromotedbyaheterogeneousgoldcatalyst

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