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Nonenzymatic Synthesis of the P-Cluster in the Nitrogenase MoFe Protein: Evidence of the Involvement of All-Ferrous [Fe(4)S(4)](0) Intermediates
[Image: see text] The P-cluster in the nitrogenase MoFe protein is a [Fe(8)S(7)] cluster and represents the most complex FeS cluster found in Nature. To date, the exact mechanism of the in vivo synthesis of the P-cluster remains unclear. What is known is that the precursor to the P-cluster is a pair...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3970913/ https://www.ncbi.nlm.nih.gov/pubmed/24520862 http://dx.doi.org/10.1021/bi401699u |