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Effect of the Phosphine Steric and Electronic Profile on the Rh-Promoted Dehydrocoupling of Phosphine–Boranes
[Image: see text] The electronic and steric effects in the stoichiometric dehydrocoupling of secondary and primary phosphine–boranes H(3)B·PR(2)H [R = 3,5-(CF(3))(2)C(6)H(3); p-(CF(3))C(6)H(4); p-(OMe)C(6)H(4); adamantyl, Ad] and H(3)B·PCyH(2) to form the metal-bound linear diboraphosphines H(3)B·PR...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3979130/ https://www.ncbi.nlm.nih.gov/pubmed/24617924 http://dx.doi.org/10.1021/ic500032f |