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Acylammonium Salts as Dienophiles in Diels–Alder/Lactonization Organocascades

[Image: see text] α,β-Unsaturated acylammonium salts, generated in situ from commodity acid chlorides and a chiral isothiourea organocatalyst, comprise a new and versatile family of chiral dienophiles for the venerable Diels–Alder (DA) cycloaddition. Their reactivity is unveiled through a highly dia...

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Detalles Bibliográficos
Autores principales: Abbasov, Mikail E., Hudson, Brandi M., Tantillo, Dean J., Romo, Daniel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3985498/
https://www.ncbi.nlm.nih.gov/pubmed/24588428
http://dx.doi.org/10.1021/ja501005g

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