Tungsten-Catalyzed Asymmetric Epoxidation of Allylic and Homoallylic Alcohols with Hydrogen Peroxide

[Image: see text] A simple, efficient, and environmentally friendly asymmetric epoxidation of primary, secondary, tertiary allylic, and homoallylic alcohols has been accomplished. This process was promoted by a tungsten–bishydroxamic acid complex at room temperature with the use of aqueous 30% H(2)O...

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Detalles Bibliográficos
Autores principales: Wang, Chuan, Yamamoto, Hisashi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3985688/
https://www.ncbi.nlm.nih.gov/pubmed/24422626
http://dx.doi.org/10.1021/ja411379e
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author Wang, Chuan
Yamamoto, Hisashi
author_facet Wang, Chuan
Yamamoto, Hisashi
author_sort Wang, Chuan
collection PubMed
description [Image: see text] A simple, efficient, and environmentally friendly asymmetric epoxidation of primary, secondary, tertiary allylic, and homoallylic alcohols has been accomplished. This process was promoted by a tungsten–bishydroxamic acid complex at room temperature with the use of aqueous 30% H(2)O(2) as oxidant, yielding the products in 84–98% ee.
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spelling pubmed-39856882015-01-14 Tungsten-Catalyzed Asymmetric Epoxidation of Allylic and Homoallylic Alcohols with Hydrogen Peroxide Wang, Chuan Yamamoto, Hisashi J Am Chem Soc [Image: see text] A simple, efficient, and environmentally friendly asymmetric epoxidation of primary, secondary, tertiary allylic, and homoallylic alcohols has been accomplished. This process was promoted by a tungsten–bishydroxamic acid complex at room temperature with the use of aqueous 30% H(2)O(2) as oxidant, yielding the products in 84–98% ee. American Chemical Society 2014-01-14 2014-01-29 /pmc/articles/PMC3985688/ /pubmed/24422626 http://dx.doi.org/10.1021/ja411379e Text en Copyright © 2014 American Chemical Society
spellingShingle Wang, Chuan
Yamamoto, Hisashi
Tungsten-Catalyzed Asymmetric Epoxidation of Allylic and Homoallylic Alcohols with Hydrogen Peroxide
title Tungsten-Catalyzed Asymmetric Epoxidation of Allylic and Homoallylic Alcohols with Hydrogen Peroxide
title_full Tungsten-Catalyzed Asymmetric Epoxidation of Allylic and Homoallylic Alcohols with Hydrogen Peroxide
title_fullStr Tungsten-Catalyzed Asymmetric Epoxidation of Allylic and Homoallylic Alcohols with Hydrogen Peroxide
title_full_unstemmed Tungsten-Catalyzed Asymmetric Epoxidation of Allylic and Homoallylic Alcohols with Hydrogen Peroxide
title_short Tungsten-Catalyzed Asymmetric Epoxidation of Allylic and Homoallylic Alcohols with Hydrogen Peroxide
title_sort tungsten-catalyzed asymmetric epoxidation of allylic and homoallylic alcohols with hydrogen peroxide
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3985688/
https://www.ncbi.nlm.nih.gov/pubmed/24422626
http://dx.doi.org/10.1021/ja411379e
work_keys_str_mv AT wangchuan tungstencatalyzedasymmetricepoxidationofallylicandhomoallylicalcoholswithhydrogenperoxide
AT yamamotohisashi tungstencatalyzedasymmetricepoxidationofallylicandhomoallylicalcoholswithhydrogenperoxide

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