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Fast Proton-Coupled Electron Transfer Observed for a High-Fidelity Structural and Functional [2Fe–2S] Rieske Model
[Image: see text] Rieske cofactors have a [2Fe–2S] cluster with unique {His(2)Cys(2)} ligation and distinct Fe subsites. The histidine ligands are functionally relevant, since they allow for coupling of electron and proton transfer (PCET) during quinol oxidation in respiratory and photosynthetic ET...
Autores principales: | Albers, Antonia, Demeshko, Serhiy, Dechert, Sebastian, Saouma, Caroline T., Mayer, James M., Meyer, Franc |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2014
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3985845/ https://www.ncbi.nlm.nih.gov/pubmed/24506804 http://dx.doi.org/10.1021/ja412449v |
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