Development of a Suzuki Cross-Coupling Reaction between 2-Azidoarylboronic Pinacolate Esters and Vinyl Triflates To Enable the Synthesis of [2,3]-Fused Indole Heterocycles

[Image: see text] The scope and limitations of a Suzuki reaction between 2-azidoarylboronic acid pinacolate esters and vinyl triflates are reported. This cross-coupling reaction enables the regioselective synthesis of indoles after a subsequent Rh(II)(2)-catalyzed sp(2)-C–H bond amination reaction....

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Autores principales: Jana, Navendu, Nguyen, Quyen, Driver, Tom G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3985933/
https://www.ncbi.nlm.nih.gov/pubmed/24571492
http://dx.doi.org/10.1021/jo500252e
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author Jana, Navendu
Nguyen, Quyen
Driver, Tom G.
author_facet Jana, Navendu
Nguyen, Quyen
Driver, Tom G.
author_sort Jana, Navendu
collection PubMed
description [Image: see text] The scope and limitations of a Suzuki reaction between 2-azidoarylboronic acid pinacolate esters and vinyl triflates are reported. This cross-coupling reaction enables the regioselective synthesis of indoles after a subsequent Rh(II)(2)-catalyzed sp(2)-C–H bond amination reaction.
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spelling pubmed-39859332015-02-27 Development of a Suzuki Cross-Coupling Reaction between 2-Azidoarylboronic Pinacolate Esters and Vinyl Triflates To Enable the Synthesis of [2,3]-Fused Indole Heterocycles Jana, Navendu Nguyen, Quyen Driver, Tom G. J Org Chem [Image: see text] The scope and limitations of a Suzuki reaction between 2-azidoarylboronic acid pinacolate esters and vinyl triflates are reported. This cross-coupling reaction enables the regioselective synthesis of indoles after a subsequent Rh(II)(2)-catalyzed sp(2)-C–H bond amination reaction. American Chemical Society 2014-02-27 2014-03-21 /pmc/articles/PMC3985933/ /pubmed/24571492 http://dx.doi.org/10.1021/jo500252e Text en Copyright © 2014 American Chemical Society
spellingShingle Jana, Navendu
Nguyen, Quyen
Driver, Tom G.
Development of a Suzuki Cross-Coupling Reaction between 2-Azidoarylboronic Pinacolate Esters and Vinyl Triflates To Enable the Synthesis of [2,3]-Fused Indole Heterocycles
title Development of a Suzuki Cross-Coupling Reaction between 2-Azidoarylboronic Pinacolate Esters and Vinyl Triflates To Enable the Synthesis of [2,3]-Fused Indole Heterocycles
title_full Development of a Suzuki Cross-Coupling Reaction between 2-Azidoarylboronic Pinacolate Esters and Vinyl Triflates To Enable the Synthesis of [2,3]-Fused Indole Heterocycles
title_fullStr Development of a Suzuki Cross-Coupling Reaction between 2-Azidoarylboronic Pinacolate Esters and Vinyl Triflates To Enable the Synthesis of [2,3]-Fused Indole Heterocycles
title_full_unstemmed Development of a Suzuki Cross-Coupling Reaction between 2-Azidoarylboronic Pinacolate Esters and Vinyl Triflates To Enable the Synthesis of [2,3]-Fused Indole Heterocycles
title_short Development of a Suzuki Cross-Coupling Reaction between 2-Azidoarylboronic Pinacolate Esters and Vinyl Triflates To Enable the Synthesis of [2,3]-Fused Indole Heterocycles
title_sort development of a suzuki cross-coupling reaction between 2-azidoarylboronic pinacolate esters and vinyl triflates to enable the synthesis of [2,3]-fused indole heterocycles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3985933/
https://www.ncbi.nlm.nih.gov/pubmed/24571492
http://dx.doi.org/10.1021/jo500252e
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AT nguyenquyen developmentofasuzukicrosscouplingreactionbetween2azidoarylboronicpinacolateestersandvinyltriflatestoenablethesynthesisof23fusedindoleheterocycles
AT drivertomg developmentofasuzukicrosscouplingreactionbetween2azidoarylboronicpinacolateestersandvinyltriflatestoenablethesynthesisof23fusedindoleheterocycles

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