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Total Synthesis of 7′-Desmethylkealiiquinone, 4′-Desmethoxykealiiquinone, and 2-Deoxykealiiquinone

[Image: see text] Synthetic approaches to the imidazonaphthoquinone core of kealiiquinone and related Leucetta-derived alkaloids are described. The polysubstituted benzimidazole framework can be constructed through intramolecular Diels–Alder reactions of propiolate-derived enynes followed by oxidati...

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Detalles Bibliográficos
Autores principales: Lima, Heather M., Sivappa, Rasapalli, Yousufuddin, Muhammed, Lovely, Carl J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3986028/
https://www.ncbi.nlm.nih.gov/pubmed/24533685
http://dx.doi.org/10.1021/jo4027337