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Alkoxyboration: Ring-Closing Addition of B–O σ Bonds across Alkynes

[Image: see text] For nearly 70 years, the addition of boron–X σ bonds to carbon–carbon multiple bonds has been employed in the preparation of organoboron reagents. However, the significantly higher strength of boron–oxygen bonds has thus far precluded their activation for addition, preventing a dir...

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Detalles Bibliográficos
Autores principales: Hirner, Joshua J., Faizi, Darius J., Blum, Suzanne A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3986241/
https://www.ncbi.nlm.nih.gov/pubmed/24588331
http://dx.doi.org/10.1021/ja500463p