Triptycene-Based Organic Molecules of Intrinsic Microporosity

[Image: see text] Four Organic Molecules of Intrinsic Microporosity (OMIMs) were prepared by fusing triptycene-based components to a biphenyl core. Due to their rigid molecular structures that cannot pack space efficiently, these OMIMs form amorphous materials with significant microporosity as demon...

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Autores principales: Taylor, Rupert G. D., Carta, Mariolino, Bezzu, C. Grazia, Walker, Jonathan, Msayib, Kadhum J., Kariuki, Benson M., McKeown, Neil B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3991315/
https://www.ncbi.nlm.nih.gov/pubmed/24635193
http://dx.doi.org/10.1021/ol500591q
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author Taylor, Rupert G. D.
Carta, Mariolino
Bezzu, C. Grazia
Walker, Jonathan
Msayib, Kadhum J.
Kariuki, Benson M.
McKeown, Neil B.
author_facet Taylor, Rupert G. D.
Carta, Mariolino
Bezzu, C. Grazia
Walker, Jonathan
Msayib, Kadhum J.
Kariuki, Benson M.
McKeown, Neil B.
author_sort Taylor, Rupert G. D.
collection PubMed
description [Image: see text] Four Organic Molecules of Intrinsic Microporosity (OMIMs) were prepared by fusing triptycene-based components to a biphenyl core. Due to their rigid molecular structures that cannot pack space efficiently, these OMIMs form amorphous materials with significant microporosity as demonstrated by apparent BET surface areas in the range of 515–702 m(2) g(–1). Bulky cyclic 1′,2′,3′,4′-tetrahydro-1′,1′,4′,4′-tetramethylbenzo units placed on the triptycene termini are especially efficient at enhancing microporosity.
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spelling pubmed-39913152014-04-18 Triptycene-Based Organic Molecules of Intrinsic Microporosity Taylor, Rupert G. D. Carta, Mariolino Bezzu, C. Grazia Walker, Jonathan Msayib, Kadhum J. Kariuki, Benson M. McKeown, Neil B. Org Lett [Image: see text] Four Organic Molecules of Intrinsic Microporosity (OMIMs) were prepared by fusing triptycene-based components to a biphenyl core. Due to their rigid molecular structures that cannot pack space efficiently, these OMIMs form amorphous materials with significant microporosity as demonstrated by apparent BET surface areas in the range of 515–702 m(2) g(–1). Bulky cyclic 1′,2′,3′,4′-tetrahydro-1′,1′,4′,4′-tetramethylbenzo units placed on the triptycene termini are especially efficient at enhancing microporosity. American Chemical Society 2014-03-17 2014-04-04 /pmc/articles/PMC3991315/ /pubmed/24635193 http://dx.doi.org/10.1021/ol500591q Text en Copyright © 2014 American Chemical Society Terms of Use CC-BY (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html)
spellingShingle Taylor, Rupert G. D.
Carta, Mariolino
Bezzu, C. Grazia
Walker, Jonathan
Msayib, Kadhum J.
Kariuki, Benson M.
McKeown, Neil B.
Triptycene-Based Organic Molecules of Intrinsic Microporosity
title Triptycene-Based Organic Molecules of Intrinsic Microporosity
title_full Triptycene-Based Organic Molecules of Intrinsic Microporosity
title_fullStr Triptycene-Based Organic Molecules of Intrinsic Microporosity
title_full_unstemmed Triptycene-Based Organic Molecules of Intrinsic Microporosity
title_short Triptycene-Based Organic Molecules of Intrinsic Microporosity
title_sort triptycene-based organic molecules of intrinsic microporosity
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3991315/
https://www.ncbi.nlm.nih.gov/pubmed/24635193
http://dx.doi.org/10.1021/ol500591q
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