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Beyond the Roche Ester: A New Approach to Polypropionate Stereotriad Synthesis
[Image: see text] An efficient, step-economical, and scalable approach to the synthesis of polypropionate stereotriads has been developed. Either 2-butyne or propyne is subjected to rhodium-catalyzed silylformylation and in situ crotylation of the resulting aldehydes. Tamao oxidation under either “s...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3993613/ https://www.ncbi.nlm.nih.gov/pubmed/24502345 http://dx.doi.org/10.1021/ol500051e |