Diels–Alder Construction of Regiodifferentiated meta-Amino Phenols and Derivatives

[Image: see text] Synthetic access to regiodifferentiated meta-amino phenols is described. The strategy relies upon distinct deprotonation conditions to afford regioisomeric thermodynamic and kinetic dienes that undergo a tandem Diels–Alder and retro-Diels–Alder sequence with assorted acetylenic die...

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Autores principales: Weaver, Marisa G., Bai, Wen-Ju, Jackson, Stephen K., Pettus, Thomas R. R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3993616/
https://www.ncbi.nlm.nih.gov/pubmed/24524325
http://dx.doi.org/10.1021/ol4034447
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author Weaver, Marisa G.
Bai, Wen-Ju
Jackson, Stephen K.
Pettus, Thomas R. R.
author_facet Weaver, Marisa G.
Bai, Wen-Ju
Jackson, Stephen K.
Pettus, Thomas R. R.
author_sort Weaver, Marisa G.
collection PubMed
description [Image: see text] Synthetic access to regiodifferentiated meta-amino phenols is described. The strategy relies upon distinct deprotonation conditions to afford regioisomeric thermodynamic and kinetic dienes that undergo a tandem Diels–Alder and retro-Diels–Alder sequence with assorted acetylenic dienophiles to afford a range of aromatic products.
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spelling pubmed-39936162015-02-13 Diels–Alder Construction of Regiodifferentiated meta-Amino Phenols and Derivatives Weaver, Marisa G. Bai, Wen-Ju Jackson, Stephen K. Pettus, Thomas R. R. Org Lett [Image: see text] Synthetic access to regiodifferentiated meta-amino phenols is described. The strategy relies upon distinct deprotonation conditions to afford regioisomeric thermodynamic and kinetic dienes that undergo a tandem Diels–Alder and retro-Diels–Alder sequence with assorted acetylenic dienophiles to afford a range of aromatic products. American Chemical Society 2014-02-13 2014-03-07 /pmc/articles/PMC3993616/ /pubmed/24524325 http://dx.doi.org/10.1021/ol4034447 Text en Copyright © 2014 American Chemical Society
spellingShingle Weaver, Marisa G.
Bai, Wen-Ju
Jackson, Stephen K.
Pettus, Thomas R. R.
Diels–Alder Construction of Regiodifferentiated meta-Amino Phenols and Derivatives
title Diels–Alder Construction of Regiodifferentiated meta-Amino Phenols and Derivatives
title_full Diels–Alder Construction of Regiodifferentiated meta-Amino Phenols and Derivatives
title_fullStr Diels–Alder Construction of Regiodifferentiated meta-Amino Phenols and Derivatives
title_full_unstemmed Diels–Alder Construction of Regiodifferentiated meta-Amino Phenols and Derivatives
title_short Diels–Alder Construction of Regiodifferentiated meta-Amino Phenols and Derivatives
title_sort diels–alder construction of regiodifferentiated meta-amino phenols and derivatives
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3993616/
https://www.ncbi.nlm.nih.gov/pubmed/24524325
http://dx.doi.org/10.1021/ol4034447
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