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Aminodiols via Stereocontrolled Oxidation of Methyleneaziridines
[Image: see text] A highly diastereoselective Ru-catalyzed oxidation/reduction sequence of bicyclic methyleneaziridines provides a facile route to complex 1-amino-2,3-diol motifs. The relative anti stereochemistry between the amine and the vicinal alcohol are proposed to result from 1,3-bischelation...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3993784/ https://www.ncbi.nlm.nih.gov/pubmed/24617556 http://dx.doi.org/10.1021/ol5003576 |