Cargando…

Palladium-Catalyzed α-Arylation of Benzylic Phosphonates

[Image: see text] A new synthetic route to access diarylmethyl phosphonates is presented. The transformation enables the introduction of aromatic groups on benzylic phosphonates via a deprotonative cross-coupling process (DCCP). The Pd(OAc)(2)/CataCXium A-based catalyst afforded a reaction between b...

Descripción completa

Detalles Bibliográficos
Autores principales:	Montel, Sonia, Raffier, Ludovic, He, Yuying, Walsh, Patrick J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3993846/ https://www.ncbi.nlm.nih.gov/pubmed/24520897 http://dx.doi.org/10.1021/ol5002413

Ejemplares similares

Palladium-catalyzed benzylic C(sp(3))–H carbonylative arylation of azaarylmethyl amines with aryl bromides
por: Zhao, Haoqiang, et al.
Publicado: (2021)

Palladium-Catalyzed α-Arylation of Aryl Nitromethanes
por: VanGelder, Kelsey F., et al.
Publicado: (2015)

Palladium-Catalyzed α-Arylation of Aryl Acetic Acid Derivatives via Dienolate Intermediates with Aryl Chlorides and Bromides
por: Sha, Sheng-Chun, et al.
Publicado: (2015)

Palladium-catalyzed α-arylation for the addition of small rings to aromatic compounds
por: He, Zhi-Tao, et al.
Publicado: (2019)

Palladium-Catalyzed Regioselective Arylation of 1,1,3-Triaryl-2-azaallyl Anions with Aryl Chlorides
por: Li, Minyan, et al.
Publicado: (2014)

Palladium-catalyzed α-arylation of carbonyls in the de novo synthesis of aromatic heterocycles
por: Potukuchi, Harish K., et al.
Publicado: (2015)

Chemoselective palladium-catalyzed deprotonative arylation/[1,2]-Wittig rearrangement of pyridylmethyl ethers
por: Gao, Feng, et al.
Publicado: (2016)

Reactivity of bromoselenophenes in palladium-catalyzed direct arylations
por: Skhiri, Aymen, et al.
Publicado: (2017)

Palladium-Catalyzed Regioselective Arylation of Unprotected Allylamines
por: Landge, Vinod G., et al.
Publicado: (2020)

Electronically flexible PYA ligands for efficient palladium-catalyzed α-arylation of ketones
por: Reusser, Esaïe, et al.
Publicado: (2023)

Palladium Catalyzed Heck Arylation of 2,3-Dihydrofuran—Effect of the Palladium Precursor
por: Morel, Adam, et al.
Publicado: (2014)

Palladium-Catalyzed Oxidative Domino Carbocyclization–Arylation of Bisallenes
por: Volla, Chandra M. R., et al.
Publicado: (2016)

Efficient Palladium‐Catalyzed Aerobic Arylative Carbocyclization of Enallenynes
por: Liu, Jie, et al.
Publicado: (2018)

Palladium-Catalyzed Sulfinylation of Aryl- and Alkenylborons with Sulfinate Esters
por: Suzuki, Minori, et al.
Publicado: (2021)

Enantioselective amine α-functionalization via palladium catalyzed C–H arylation of thioamides
por: Jain, Pankaj, et al.
Publicado: (2016)

Palladium-catalyzed cross-coupling of α-bromocarbonyls and allylic alcohols for the synthesis of α-aryl dicarbonyl compounds
por: Yu, Yang, et al.
Publicado: (2015)

Enantioselective synthesis of α-amino ketones through palladium-catalyzed asymmetric arylation of α-keto imines
por: Wen, Wei, et al.
Publicado: (2022)

Palladium-Catalyzed Amination of Aryl Chlorides and Bromides with Ammonium Salts
por: Green, Rebecca A., et al.
Publicado: (2014)

Efficient Palladium-Catalyzed Synthesis of 2-Aryl Propionic Acids
por: Neumann, Helfried, et al.
Publicado: (2020)

Recent advances and prospects in the palladium-catalyzed cyanation of aryl halides
por: Neetha, Mohan, et al.
Publicado: (2020)

Palladium-catalyzed intermolecular transthioetherification of aryl halides with thioethers and thioesters
por: Li, Yahui, et al.
Publicado: (2020)

Palladium-Catalyzed N-Alkenylation of N-Aryl Phosphoramidates with Alkenes
por: Li, Yu-An, et al.
Publicado: (2023)

Aryl acrylonitriles synthesis enabled by palladium-catalyzed α-alkenylation of arylacetonitriles with vinyl halides/triflates
por: Jiang, Yonggang, et al.
Publicado: (2022)

Palladium-Catalyzed Allylation/Benzylation of H-Phosphinate Esters with Alcohols
por: Fers-Lidou, Anthony, et al.
Publicado: (2016)

NiXantphos: A Deprotonatable Ligand for Room-Temperature Palladium-Catalyzed Cross-Couplings of Aryl Chlorides
por: Zhang, Jiadi, et al.
Publicado: (2014)

Synthesis of C(2)-Symmetric Benzimidazolium Salts and Their Application in Palladium-Catalyzed Enantioselective Intramolecular α-Arylation of Amides
por: He, Weiping, et al.
Publicado: (2016)

Palladium‐Catalyzed para‐C−H Arylation of Anilines with Aromatic Halides
por: Lichte, Dominik, et al.
Publicado: (2022)

Palladium-catalyzed chemoselective direct α-arylation of carbonyl compounds with chloroaryl triflates at the C–Cl site
por: Chen, Zicong, et al.
Publicado: (2022)

Olefin‐Directed Palladium‐Catalyzed Regio‐ and Stereoselective Oxidative Arylation of Allenes
por: Zhu, Can, et al.
Publicado: (2015)

Palladium-Catalyzed C–H Arylation of 1,2,3-Triazoles
por: Zhang, Chengwei, et al.
Publicado: (2016)

Palladium-catalyzed difluoromethylthiolation of heteroaryl bromides, iodides, triflates and aryl iodides
por: Wu, Jiang, et al.
Publicado: (2016)

Palladium-Catalyzed Decarboxylative Coupling of Alkynyl Carboxylic Acids with Aryl Tosylates
por: Lee, Ju-Hyeon, et al.
Publicado: (2017)

Palladium-Catalyzed Intramolecular Oxidative Arylations for the Synthesis of Fused Biaryl Sulfones
por: Laha, Joydev K., et al.
Publicado: (2018)

Palladium-catalyzed solid-state borylation of aryl halides using mechanochemistry
por: Kubota, Koji, et al.
Publicado: (2022)

Mechanistic Studies of the Palladium-Catalyzed Desulfinative Cross-Coupling of Aryl Bromides and (Hetero)Aryl Sulfinate Salts
por: de Gombert, Antoine, et al.
Publicado: (2020)

Phosphonic acid mediated practical dehalogenation and benzylation with benzyl halides
por: Xiao, Jing, et al.
Publicado: (2019)

Synthesis of Fluorinated Alkyl Aryl Ethers by Palladium-Catalyzed C–O Cross-Coupling
por: Szpera, Robert, et al.
Publicado: (2020)

Short and Efficient Syntheses of Protoberberine Alkaloids using Palladium-Catalyzed Enolate Arylation**
por: Gatland, Alice E, et al.
Publicado: (2014)

Facilitating the transmetalation step with aryl-zincates in nickel-catalyzed enantioselective arylation of secondary benzylic halides
por: Huang, Weichen, et al.
Publicado: (2019)

Palladium-Catalyzed α-Arylation of Cyclic β-Dicarbonyl Compounds for the Synthesis of Ca(V)1.3 Inhibitors
por: Yun, Jisu, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_4hem05ob96dlvpq428licf1qb7