Cargando…

Iron-Catalyzed Arylation of Heterocycles via Directed C–H Bond Activation

[Image: see text] The iron-catalyzed arylation of aromatic heterocycles, such as pyridines, thiophenes, and furans, has been achieved. The use of an imine directing group allowed for the ortho functionalization of these heterocycles with complete conversion in 15 min at 0 °C. Yields up to 88% were o...

Descripción completa

Detalles Bibliográficos
Autores principales:	Sirois, John J., Davis, Riley, DeBoef, Brenton
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3993849/ https://www.ncbi.nlm.nih.gov/pubmed/24450989 http://dx.doi.org/10.1021/ol403634b

Ejemplares similares

Correction to Iron-Catalyzed Arylation of Heterocycles via Directed C–H Bond Activation
por: Sirois, John J., et al.
Publicado: (2014)

Regioselective Gold-Catalyzed Oxidative C–N Bond Formation
por: Marchetti, Louis, et al.
Publicado: (2014)

Cobalt-catalyzed, directed arylation of C–H bonds in N-aryl pyrazoles
por: Nguyen, Tung T., et al.
Publicado: (2021)

Correction: Cobalt-catalyzed, directed arylation of C–H bonds in N-aryl pyrazoles
por: Nguyen, Tung T., et al.
Publicado: (2021)

Pyridylidene ligand facilitates gold-catalyzed oxidative C–H arylation of heterocycles
por: Hata, Kazuhiro, et al.
Publicado: (2015)

FeCl(2)-Mediated Rearrangement of Allylic Alcohols
por: Oppong-Quaicoe, Anita A., et al.
Publicado: (2019)

Thioketone-directed rhodium(I) catalyzed enantioselective C-H bond arylation of ferrocenes
por: Cai, Zhong-Jian, et al.
Publicado: (2019)

Palladium‐Catalyzed Directed C(sp(3))–H Arylation of Saturated Heterocycles at C‐3 Using a Concise Optimization Approach
por: Affron, Dominic P., et al.
Publicado: (2015)

Infrared Irradiation‐Assisted Solvent‐Free Pd‐Catalyzed (Hetero)aryl‐aryl Coupling via C−H Bond Activation
por: Albano, Gianluigi, et al.
Publicado: (2021)

Direct Arylation of Strong Aliphatic C–H Bonds
por: Perry, Ian B., et al.
Publicado: (2018)

Palladium-Catalyzed C–P Bond-Forming Reactions of Aryl Nonaflates Accelerated by Iodide
por: McErlain, Holly, et al.
Publicado: (2021)

Ni(ii)-catalyzed mono-selective ortho-arylation of unactivated aryl C–H bonds utilizing amino acids as a directing group
por: Cong, Zhanqing, et al.
Publicado: (2019)

Pd(II)-catalyzed ortho arylation of 2-arylbenzothiazoles with aryl iodides via benzothiazole-directed C–H activation
por: Ding, Qiuping, et al.
Publicado: (2012)

Palladium-Catalyzed Arylation of C(sp(2))–H Bonds with 2-(1-Methylhydrazinyl)pyridine as the Bidentate Directing Group
por: Wei, Jian, et al.
Publicado: (2021)

Ru-Catalyzed C–H Arylation of Fluoroarenes with Aryl Halides
por: Simonetti, Marco, et al.
Publicado: (2016)

Highly Efficient and Reusable Copper-Catalyzed N-Arylation of Nitrogen-Containing Heterocycles with Aryl Halides
por: Kim, A Young, et al.
Publicado: (2009)

Copper-catalyzed direct C–H arylselenation of 4-nitro-pyrazoles and other heterocycles with selenium powder and aryl iodides. Access to unsymmetrical heteroaryl selenides
por: Jakubczyk, Michał, et al.
Publicado: (2019)

Silver-Free Gold-Catalyzed Heterocyclizations through Intermolecular H-Bonding Activation
por: Elías-Rodríguez, Pilar, et al.
Publicado: (2023)

Synthesis of 5,6-Dihydrophenanthridines via Palladium-Catalyzed Intramolecular Dehydrogenative Coupling of Two Aryl C−H Bonds
por: Wang, Meng-Yue, et al.
Publicado: (2023)

Synthesis of (diarylmethyl)amines using Ni-catalyzed arylation of C(sp(3))–H bonds
por: Fernández-Salas, José A., et al.
Publicado: (2015)

The direct arylation of allylic sp(3) C–H bonds via organocatalysis and photoredox catalysis
por: Cuthbertson, James D., et al.
Publicado: (2015)

Effect of α-Substitution on the Reactivity of C(sp(3))–H Bonds in Pd(0)-Catalyzed C–H Arylation
por: Wheatley, Matthew, et al.
Publicado: (2023)

Carbonylative N-Heterocyclization via Nitrogen-Directed C–C Bond Activation of Nonactivated Cyclopropanes
por: Calow, Adam D. J., et al.
Publicado: (2022)

Palladium-catalyzed α-arylation of carbonyls in the de novo synthesis of aromatic heterocycles
por: Potukuchi, Harish K., et al.
Publicado: (2015)

Palladium(II)-Catalyzed Regioselective Ortho Arylation of sp(2) C—H Bonds of N-Aryl-2-amino Pyridine Derivatives
por: Koley, Moumita, et al.
Publicado: (2012)

Synthesis of β-arylated alkylamides via Pd-catalyzed one-pot installation of a directing group and C(sp(3))–H arylation
por: Liu, Yunyun, et al.
Publicado: (2016)

Ruthenium-Catalyzed C–H Arylation of Diverse Aryl Carboxylic Acids with Aryl and Heteroaryl Halides
por: Huang, Liangbin, et al.
Publicado: (2016)

δ C–H (hetero)arylation via Cu-catalyzed radical relay
por: Zhang, Zuxiao, et al.
Publicado: (2018)

Strategies for palladium-catalyzed non-directed and directed C-H bond functionalization
por: Kapdi, Anant R, et al.
Publicado: (2017)

Gold-Catalyzed C–H Functionalization with Aryl Germanes
por: Fricke, Christoph, et al.
Publicado: (2019)

Iron-Catalyzed Asymmetric Hydrosilylation of Vinylcyclopropanes via Stereospecific C-C Bond Cleavage
por: Chen, Chenhui, et al.
Publicado: (2020)

Palladium-Catalyzed trans-Hydroalkoxylation: Counterintuitive Use of an Aryl Iodide Additive to Promote C–H Bond Formation
por: Das, Ashis, et al.
Publicado: (2022)

N-Heterocyclic carbene–palladium catalysts for the direct arylation of pyrrole derivatives with aryl chlorides
por: Özdemir, Ismail, et al.
Publicado: (2013)

Pd‐Catalyzed Directed Thiocyanation Reaction by C−H Bond Activation
por: Gao, Mélissa, et al.
Publicado: (2020)

Rhodium-catalyzed selective direct arylation of phosphines with aryl bromides
por: Wang, Dingyi, et al.
Publicado: (2022)

Rh(iii)-catalyzed C-7 arylation of indolines with arylsilanes via C–H activation
por: Luo, Haiqing, et al.
Publicado: (2019)

Enantioselective amine α-functionalization via palladium catalyzed C–H arylation of thioamides
por: Jain, Pankaj, et al.
Publicado: (2016)

Synthesis of Planar Chiral Ferroceneformaldehydes via Rh(I)-Catalyzed C–H Arylation
por: Hendricks, Hailey, et al.
Publicado: (2023)

First selective direct mono-arylation of piperidines using ruthenium-catalyzed C–H activation
por: Schwarz, Maria C., et al.
Publicado: (2013)

Iron(II)‐Catalyzed Aerobic Biomimetic Oxidation of N‐Heterocycles
por: Manna, Srimanta, et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_vjb3kdc11sb07sf3aaq5kl6hp4