Recyclable Polystyrene-Supported Siloxane-Transfer Agent for Palladium-Catalyzed Cross-Coupling Reactions

[Image: see text] The rational design, synthesis, and validation of a significantly improved insoluble polymer-supported siloxane-transfer agent has been achieved that permits efficient palladium-catalyzed cross-coupling reactions. The cross-linked polystyrene support facilitates product purificatio...

Descripción completa

Detalles Bibliográficos
Autores principales: Nguyen, Minh H., Smith, Amos B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3993864/
https://www.ncbi.nlm.nih.gov/pubmed/24661113
http://dx.doi.org/10.1021/ol5007086
_version_ 1782312627156811776
author Nguyen, Minh H.
Smith, Amos B.
author_facet Nguyen, Minh H.
Smith, Amos B.
author_sort Nguyen, Minh H.
collection PubMed
description [Image: see text] The rational design, synthesis, and validation of a significantly improved insoluble polymer-supported siloxane-transfer agent has been achieved that permits efficient palladium-catalyzed cross-coupling reactions. The cross-linked polystyrene support facilitates product purification with excellent siloxane recycling. Drawbacks of a previous polymer-supported siloxane-transfer agent, relating to reaction efficiency and polymer stability after repeated cycles, have been addressed.
format Online
Article
Text
id pubmed-3993864
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-39938642015-03-24 Recyclable Polystyrene-Supported Siloxane-Transfer Agent for Palladium-Catalyzed Cross-Coupling Reactions Nguyen, Minh H. Smith, Amos B. Org Lett [Image: see text] The rational design, synthesis, and validation of a significantly improved insoluble polymer-supported siloxane-transfer agent has been achieved that permits efficient palladium-catalyzed cross-coupling reactions. The cross-linked polystyrene support facilitates product purification with excellent siloxane recycling. Drawbacks of a previous polymer-supported siloxane-transfer agent, relating to reaction efficiency and polymer stability after repeated cycles, have been addressed. American Chemical Society 2014-03-24 2014-04-04 /pmc/articles/PMC3993864/ /pubmed/24661113 http://dx.doi.org/10.1021/ol5007086 Text en Copyright © 2014 American Chemical Society
spellingShingle Nguyen, Minh H.
Smith, Amos B.
Recyclable Polystyrene-Supported Siloxane-Transfer Agent for Palladium-Catalyzed Cross-Coupling Reactions
title Recyclable Polystyrene-Supported Siloxane-Transfer Agent for Palladium-Catalyzed Cross-Coupling Reactions
title_full Recyclable Polystyrene-Supported Siloxane-Transfer Agent for Palladium-Catalyzed Cross-Coupling Reactions
title_fullStr Recyclable Polystyrene-Supported Siloxane-Transfer Agent for Palladium-Catalyzed Cross-Coupling Reactions
title_full_unstemmed Recyclable Polystyrene-Supported Siloxane-Transfer Agent for Palladium-Catalyzed Cross-Coupling Reactions
title_short Recyclable Polystyrene-Supported Siloxane-Transfer Agent for Palladium-Catalyzed Cross-Coupling Reactions
title_sort recyclable polystyrene-supported siloxane-transfer agent for palladium-catalyzed cross-coupling reactions
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3993864/
https://www.ncbi.nlm.nih.gov/pubmed/24661113
http://dx.doi.org/10.1021/ol5007086
work_keys_str_mv AT nguyenminhh recyclablepolystyrenesupportedsiloxanetransferagentforpalladiumcatalyzedcrosscouplingreactions
AT smithamosb recyclablepolystyrenesupportedsiloxanetransferagentforpalladiumcatalyzedcrosscouplingreactions

Ejemplares similares