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Guest-Adaptable and Water-Stable Peptide-Based Porous Materials by Imidazolate Side Chain Control**
The peptide-based porous 3D framework, ZnCar, has been synthesized from Zn(2+) and the natural dipeptide carnosine (β-alanyl-L-histidine). Unlike previous extended peptide networks, the imidazole side chain of the histidine residue is deprotonated to afford Zn–imidazolate chains, with bonding simila...
Autores principales: | , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Wiley-VCH Verlag GmbH & Co
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3995008/ https://www.ncbi.nlm.nih.gov/pubmed/24302659 http://dx.doi.org/10.1002/anie.201307074 |