(5-Methyl­pyrazine-2-carboxyl­ato-κ(2) N (1),O)bis­[2-(4-methyl­pyridin-2-yl-κN)-3,5-bis­(tri­fluoro­meth­yl)phenyl-κC (1)]iridium(III) chloro­form hemisolvate

In the title complex, [Ir(C(14)H(8)F(6)N)(2)(C(6)H(5)N(2)O(2))]·0.5CHCl(3), the Ir(III) atom adopts a distorted octa­hedral geometry, being coordinated by three N atoms (arranged meridionally), two C atoms and one O atom of three bidentate ligands. The complex mol­ecules pack with no specific inter­...

Descripción completa

Detalles Bibliográficos
Autores principales: Kim, Young-Inn, Song, Young-Kwang, Kang, Sung Kwon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998247/
https://www.ncbi.nlm.nih.gov/pubmed/24764808
http://dx.doi.org/10.1107/S1600536813034727
_version_ 1782313319862894592
author Kim, Young-Inn
Song, Young-Kwang
Kang, Sung Kwon
author_facet Kim, Young-Inn
Song, Young-Kwang
Kang, Sung Kwon
author_sort Kim, Young-Inn
collection PubMed
description In the title complex, [Ir(C(14)H(8)F(6)N)(2)(C(6)H(5)N(2)O(2))]·0.5CHCl(3), the Ir(III) atom adopts a distorted octa­hedral geometry, being coordinated by three N atoms (arranged meridionally), two C atoms and one O atom of three bidentate ligands. The complex mol­ecules pack with no specific inter­molecular inter­actions between them. The SQUEEZE procedure in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155] was used to model a disordered chloro­form solvent mol­ecule; the calculated unit-cell data allow for the presence of half of this mol­ecule in the asymmetric unit.
format Online
Article
Text
id pubmed-3998247
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-39982472014-04-24 (5-Methyl­pyrazine-2-carboxyl­ato-κ(2) N (1),O)bis­[2-(4-methyl­pyridin-2-yl-κN)-3,5-bis­(tri­fluoro­meth­yl)phenyl-κC (1)]iridium(III) chloro­form hemisolvate Kim, Young-Inn Song, Young-Kwang Kang, Sung Kwon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ir(C(14)H(8)F(6)N)(2)(C(6)H(5)N(2)O(2))]·0.5CHCl(3), the Ir(III) atom adopts a distorted octa­hedral geometry, being coordinated by three N atoms (arranged meridionally), two C atoms and one O atom of three bidentate ligands. The complex mol­ecules pack with no specific inter­molecular inter­actions between them. The SQUEEZE procedure in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155] was used to model a disordered chloro­form solvent mol­ecule; the calculated unit-cell data allow for the presence of half of this mol­ecule in the asymmetric unit. International Union of Crystallography 2014-01-08 /pmc/articles/PMC3998247/ /pubmed/24764808 http://dx.doi.org/10.1107/S1600536813034727 Text en © Kim et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kim, Young-Inn
Song, Young-Kwang
Kang, Sung Kwon
(5-Methyl­pyrazine-2-carboxyl­ato-κ(2) N (1),O)bis­[2-(4-methyl­pyridin-2-yl-κN)-3,5-bis­(tri­fluoro­meth­yl)phenyl-κC (1)]iridium(III) chloro­form hemisolvate
title (5-Methyl­pyrazine-2-carboxyl­ato-κ(2) N (1),O)bis­[2-(4-methyl­pyridin-2-yl-κN)-3,5-bis­(tri­fluoro­meth­yl)phenyl-κC (1)]iridium(III) chloro­form hemisolvate
title_full (5-Methyl­pyrazine-2-carboxyl­ato-κ(2) N (1),O)bis­[2-(4-methyl­pyridin-2-yl-κN)-3,5-bis­(tri­fluoro­meth­yl)phenyl-κC (1)]iridium(III) chloro­form hemisolvate
title_fullStr (5-Methyl­pyrazine-2-carboxyl­ato-κ(2) N (1),O)bis­[2-(4-methyl­pyridin-2-yl-κN)-3,5-bis­(tri­fluoro­meth­yl)phenyl-κC (1)]iridium(III) chloro­form hemisolvate
title_full_unstemmed (5-Methyl­pyrazine-2-carboxyl­ato-κ(2) N (1),O)bis­[2-(4-methyl­pyridin-2-yl-κN)-3,5-bis­(tri­fluoro­meth­yl)phenyl-κC (1)]iridium(III) chloro­form hemisolvate
title_short (5-Methyl­pyrazine-2-carboxyl­ato-κ(2) N (1),O)bis­[2-(4-methyl­pyridin-2-yl-κN)-3,5-bis­(tri­fluoro­meth­yl)phenyl-κC (1)]iridium(III) chloro­form hemisolvate
title_sort (5-methyl­pyrazine-2-carboxyl­ato-κ(2) n (1),o)bis­[2-(4-methyl­pyridin-2-yl-κn)-3,5-bis­(tri­fluoro­meth­yl)phenyl-κc (1)]iridium(iii) chloro­form hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998247/
https://www.ncbi.nlm.nih.gov/pubmed/24764808
http://dx.doi.org/10.1107/S1600536813034727
work_keys_str_mv AT kimyounginn 5methylpyrazine2carboxylatok2n1obis24methylpyridin2ylkn35bistrifluoromethylphenylkc1iridiumiiichloroformhemisolvate
AT songyoungkwang 5methylpyrazine2carboxylatok2n1obis24methylpyridin2ylkn35bistrifluoromethylphenylkc1iridiumiiichloroformhemisolvate
AT kangsungkwon 5methylpyrazine2carboxylatok2n1obis24methylpyridin2ylkn35bistrifluoromethylphenylkc1iridiumiiichloroformhemisolvate

Ejemplares similares