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Bis­(thio­cyanato-κN)[tris(pyridin-2-yl­meth­yl)amine-κ(4) N]­iron(II)

In the title complex, [Fe(NCS)(2)(C(18)H(18)N(4))], the Fe(II) cation is chelated by a tris­(2-pyridyl­meth­yl)amine ligand and coordin­ated by two thio­cyanate anions in a distorted N(6) octa­hedral geometry. In the crystal, weak C—H⋯S hydrogen bonds and π–π stacking inter­actions between parallel...

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Detalles Bibliográficos
Autores principales: Dai, Jing-Wei, Li, Zhao-Yang, Sato, Osamu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998248/
https://www.ncbi.nlm.nih.gov/pubmed/24764809
http://dx.doi.org/10.1107/S1600536813034818
Descripción
Sumario:In the title complex, [Fe(NCS)(2)(C(18)H(18)N(4))], the Fe(II) cation is chelated by a tris­(2-pyridyl­meth­yl)amine ligand and coordin­ated by two thio­cyanate anions in a distorted N(6) octa­hedral geometry. In the crystal, weak C—H⋯S hydrogen bonds and π–π stacking inter­actions between parallel pyridine rings of adjacent mol­ecules [centroid–centroid distance = 3.653 (3) Å] link the mol­ecules into a two-dimensional supra­molecular architecture. The structure contains voids of 124 (9) Å(3), which are free of solvent molecules.