Bis­(thio­cyanato-κN)[tris(pyridin-2-yl­meth­yl)amine-κ(4) N]­iron(II)

In the title complex, [Fe(NCS)(2)(C(18)H(18)N(4))], the Fe(II) cation is chelated by a tris­(2-pyridyl­meth­yl)amine ligand and coordin­ated by two thio­cyanate anions in a distorted N(6) octa­hedral geometry. In the crystal, weak C—H⋯S hydrogen bonds and π–π stacking inter­actions between parallel...

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Detalles Bibliográficos
Autores principales: Dai, Jing-Wei, Li, Zhao-Yang, Sato, Osamu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998248/
https://www.ncbi.nlm.nih.gov/pubmed/24764809
http://dx.doi.org/10.1107/S1600536813034818
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author Dai, Jing-Wei
Li, Zhao-Yang
Sato, Osamu
author_facet Dai, Jing-Wei
Li, Zhao-Yang
Sato, Osamu
author_sort Dai, Jing-Wei
collection PubMed
description In the title complex, [Fe(NCS)(2)(C(18)H(18)N(4))], the Fe(II) cation is chelated by a tris­(2-pyridyl­meth­yl)amine ligand and coordin­ated by two thio­cyanate anions in a distorted N(6) octa­hedral geometry. In the crystal, weak C—H⋯S hydrogen bonds and π–π stacking inter­actions between parallel pyridine rings of adjacent mol­ecules [centroid–centroid distance = 3.653 (3) Å] link the mol­ecules into a two-dimensional supra­molecular architecture. The structure contains voids of 124 (9) Å(3), which are free of solvent molecules.
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spelling pubmed-39982482014-04-24 Bis­(thio­cyanato-κN)[tris(pyridin-2-yl­meth­yl)amine-κ(4) N]­iron(II) Dai, Jing-Wei Li, Zhao-Yang Sato, Osamu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Fe(NCS)(2)(C(18)H(18)N(4))], the Fe(II) cation is chelated by a tris­(2-pyridyl­meth­yl)amine ligand and coordin­ated by two thio­cyanate anions in a distorted N(6) octa­hedral geometry. In the crystal, weak C—H⋯S hydrogen bonds and π–π stacking inter­actions between parallel pyridine rings of adjacent mol­ecules [centroid–centroid distance = 3.653 (3) Å] link the mol­ecules into a two-dimensional supra­molecular architecture. The structure contains voids of 124 (9) Å(3), which are free of solvent molecules. International Union of Crystallography 2014-01-08 /pmc/articles/PMC3998248/ /pubmed/24764809 http://dx.doi.org/10.1107/S1600536813034818 Text en © Dai et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dai, Jing-Wei
Li, Zhao-Yang
Sato, Osamu
Bis­(thio­cyanato-κN)[tris(pyridin-2-yl­meth­yl)amine-κ(4) N]­iron(II)
title Bis­(thio­cyanato-κN)[tris(pyridin-2-yl­meth­yl)amine-κ(4) N]­iron(II)
title_full Bis­(thio­cyanato-κN)[tris(pyridin-2-yl­meth­yl)amine-κ(4) N]­iron(II)
title_fullStr Bis­(thio­cyanato-κN)[tris(pyridin-2-yl­meth­yl)amine-κ(4) N]­iron(II)
title_full_unstemmed Bis­(thio­cyanato-κN)[tris(pyridin-2-yl­meth­yl)amine-κ(4) N]­iron(II)
title_short Bis­(thio­cyanato-κN)[tris(pyridin-2-yl­meth­yl)amine-κ(4) N]­iron(II)
title_sort bis­(thio­cyanato-κn)[tris(pyridin-2-yl­meth­yl)amine-κ(4) n]­iron(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998248/
https://www.ncbi.nlm.nih.gov/pubmed/24764809
http://dx.doi.org/10.1107/S1600536813034818
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