μ-1,6,7,12-Tetra­aza­perylene-κ(4) N (1),N (12):N (6),N (7)-bis­[chlorido­(η(6)-p-cymene)ruthenium(II)] bis­(hexa­fluorido­phosphate) acetone disolvate

In the title compound, [Ru(2)(C(10)H(14))(2)Cl(2)(C(16)H(8)N(4))](PF(6))(2)·2C(3)H(6)O, the binuclear Ru(II) complex dication, [{RuCl(η(6)-cym)}(2)(μ-tape)](2+), built up by a planar 1,6,7,12-tetra­aza­perylene (tape) bridge, two η(6)-bound cymene (cym) ligands and two chloride ligands, includes an...

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Autores principales: Brietzke, Thomas, Kässler, Daniel, Kelling, Alexandra, Schilde, Uwe, Holdt, Hans-Jürgen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998251/
https://www.ncbi.nlm.nih.gov/pubmed/24764812
http://dx.doi.org/10.1107/S160053681400035X
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author Brietzke, Thomas
Kässler, Daniel
Kelling, Alexandra
Schilde, Uwe
Holdt, Hans-Jürgen
author_facet Brietzke, Thomas
Kässler, Daniel
Kelling, Alexandra
Schilde, Uwe
Holdt, Hans-Jürgen
author_sort Brietzke, Thomas
collection PubMed
description In the title compound, [Ru(2)(C(10)H(14))(2)Cl(2)(C(16)H(8)N(4))](PF(6))(2)·2C(3)H(6)O, the binuclear Ru(II) complex dication, [{RuCl(η(6)-cym)}(2)(μ-tape)](2+), built up by a planar 1,6,7,12-tetra­aza­perylene (tape) bridge, two η(6)-bound cymene (cym) ligands and two chloride ligands, includes an inversion center. The Ru(II) atom shows the typical piano-stool motif for arene coordination. The counter-charge is provided by a hexa­fluorido­phosphate anion and the asymmetric unit is completed by an acetone mol­ecule of crystallization. The components of the structure are connected into a three-dimensional architecture by C—H⋯O/F/Cl inter­actions.
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spelling pubmed-39982512014-04-24 μ-1,6,7,12-Tetra­aza­perylene-κ(4) N (1),N (12):N (6),N (7)-bis­[chlorido­(η(6)-p-cymene)ruthenium(II)] bis­(hexa­fluorido­phosphate) acetone disolvate Brietzke, Thomas Kässler, Daniel Kelling, Alexandra Schilde, Uwe Holdt, Hans-Jürgen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ru(2)(C(10)H(14))(2)Cl(2)(C(16)H(8)N(4))](PF(6))(2)·2C(3)H(6)O, the binuclear Ru(II) complex dication, [{RuCl(η(6)-cym)}(2)(μ-tape)](2+), built up by a planar 1,6,7,12-tetra­aza­perylene (tape) bridge, two η(6)-bound cymene (cym) ligands and two chloride ligands, includes an inversion center. The Ru(II) atom shows the typical piano-stool motif for arene coordination. The counter-charge is provided by a hexa­fluorido­phosphate anion and the asymmetric unit is completed by an acetone mol­ecule of crystallization. The components of the structure are connected into a three-dimensional architecture by C—H⋯O/F/Cl inter­actions. International Union of Crystallography 2014-01-15 /pmc/articles/PMC3998251/ /pubmed/24764812 http://dx.doi.org/10.1107/S160053681400035X Text en © Brietzke et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Brietzke, Thomas
Kässler, Daniel
Kelling, Alexandra
Schilde, Uwe
Holdt, Hans-Jürgen
μ-1,6,7,12-Tetra­aza­perylene-κ(4) N (1),N (12):N (6),N (7)-bis­[chlorido­(η(6)-p-cymene)ruthenium(II)] bis­(hexa­fluorido­phosphate) acetone disolvate
title μ-1,6,7,12-Tetra­aza­perylene-κ(4) N (1),N (12):N (6),N (7)-bis­[chlorido­(η(6)-p-cymene)ruthenium(II)] bis­(hexa­fluorido­phosphate) acetone disolvate
title_full μ-1,6,7,12-Tetra­aza­perylene-κ(4) N (1),N (12):N (6),N (7)-bis­[chlorido­(η(6)-p-cymene)ruthenium(II)] bis­(hexa­fluorido­phosphate) acetone disolvate
title_fullStr μ-1,6,7,12-Tetra­aza­perylene-κ(4) N (1),N (12):N (6),N (7)-bis­[chlorido­(η(6)-p-cymene)ruthenium(II)] bis­(hexa­fluorido­phosphate) acetone disolvate
title_full_unstemmed μ-1,6,7,12-Tetra­aza­perylene-κ(4) N (1),N (12):N (6),N (7)-bis­[chlorido­(η(6)-p-cymene)ruthenium(II)] bis­(hexa­fluorido­phosphate) acetone disolvate
title_short μ-1,6,7,12-Tetra­aza­perylene-κ(4) N (1),N (12):N (6),N (7)-bis­[chlorido­(η(6)-p-cymene)ruthenium(II)] bis­(hexa­fluorido­phosphate) acetone disolvate
title_sort μ-1,6,7,12-tetra­aza­perylene-κ(4) n (1),n (12):n (6),n (7)-bis­[chlorido­(η(6)-p-cymene)ruthenium(ii)] bis­(hexa­fluorido­phosphate) acetone disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998251/
https://www.ncbi.nlm.nih.gov/pubmed/24764812
http://dx.doi.org/10.1107/S160053681400035X
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