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[1,4-Bis(diphenylphosphanyl)butane-κ(2) P,P′]dibromidopalladium(II)
In the title complex, [PdBr(2)(C(28)H(28)P(2))], the Pd(II) ion has a distorted cis-Br(2)P(2) square-planar coordination geometry defined by two P atoms from the chelating 1,4-bis(diphenylphosphanyl)butane ligand and two Br(−) anions. The four phenyl rings are inclined to the least-squares plane...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998252/ https://www.ncbi.nlm.nih.gov/pubmed/24764813 http://dx.doi.org/10.1107/S1600536814000774 |
Sumario: | In the title complex, [PdBr(2)(C(28)H(28)P(2))], the Pd(II) ion has a distorted cis-Br(2)P(2) square-planar coordination geometry defined by two P atoms from the chelating 1,4-bis(diphenylphosphanyl)butane ligand and two Br(−) anions. The four phenyl rings are inclined to the least-squares plane of the PdBr(2)P(2) unit [maximum deviation = 0.1294 (7) Å], making dihedral angles of 66.3 (2), 87.2 (2), 68.8 (2) and 86.8 (2)°. The butylene chain is in a gauche conformation, with a C—C—C—C torsion angle of 57.0 (8)°. Intermolecular C—H⋯Br hydrogen bonds link the complex molecules into supramolecular layers in the ab plane. Weak π–π interactions, both intra- and intermolecular [shortest inter-centroid distance = 4.598 (5) Å], are also noted in the three-dimensional architecture. |
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