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[1,4-Bis(diphenylphosphanyl)butane-κ(2) P,P′]dibromidopalladium(II)
In the title complex, [PdBr(2)(C(28)H(28)P(2))], the Pd(II) ion has a distorted cis-Br(2)P(2) square-planar coordination geometry defined by two P atoms from the chelating 1,4-bis(diphenylphosphanyl)butane ligand and two Br(−) anions. The four phenyl rings are inclined to the least-squares plane...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998252/ https://www.ncbi.nlm.nih.gov/pubmed/24764813 http://dx.doi.org/10.1107/S1600536814000774 |
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author | Ha, Kwang Song, Yo Soon |
author_facet | Ha, Kwang Song, Yo Soon |
author_sort | Ha, Kwang |
collection | PubMed |
description | In the title complex, [PdBr(2)(C(28)H(28)P(2))], the Pd(II) ion has a distorted cis-Br(2)P(2) square-planar coordination geometry defined by two P atoms from the chelating 1,4-bis(diphenylphosphanyl)butane ligand and two Br(−) anions. The four phenyl rings are inclined to the least-squares plane of the PdBr(2)P(2) unit [maximum deviation = 0.1294 (7) Å], making dihedral angles of 66.3 (2), 87.2 (2), 68.8 (2) and 86.8 (2)°. The butylene chain is in a gauche conformation, with a C—C—C—C torsion angle of 57.0 (8)°. Intermolecular C—H⋯Br hydrogen bonds link the complex molecules into supramolecular layers in the ab plane. Weak π–π interactions, both intra- and intermolecular [shortest inter-centroid distance = 4.598 (5) Å], are also noted in the three-dimensional architecture. |
format | Online Article Text |
id | pubmed-3998252 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39982522014-04-24 [1,4-Bis(diphenylphosphanyl)butane-κ(2) P,P′]dibromidopalladium(II) Ha, Kwang Song, Yo Soon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PdBr(2)(C(28)H(28)P(2))], the Pd(II) ion has a distorted cis-Br(2)P(2) square-planar coordination geometry defined by two P atoms from the chelating 1,4-bis(diphenylphosphanyl)butane ligand and two Br(−) anions. The four phenyl rings are inclined to the least-squares plane of the PdBr(2)P(2) unit [maximum deviation = 0.1294 (7) Å], making dihedral angles of 66.3 (2), 87.2 (2), 68.8 (2) and 86.8 (2)°. The butylene chain is in a gauche conformation, with a C—C—C—C torsion angle of 57.0 (8)°. Intermolecular C—H⋯Br hydrogen bonds link the complex molecules into supramolecular layers in the ab plane. Weak π–π interactions, both intra- and intermolecular [shortest inter-centroid distance = 4.598 (5) Å], are also noted in the three-dimensional architecture. International Union of Crystallography 2014-01-18 /pmc/articles/PMC3998252/ /pubmed/24764813 http://dx.doi.org/10.1107/S1600536814000774 Text en © Ha and Song 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang Song, Yo Soon [1,4-Bis(diphenylphosphanyl)butane-κ(2) P,P′]dibromidopalladium(II) |
title | [1,4-Bis(diphenylphosphanyl)butane-κ(2)
P,P′]dibromidopalladium(II) |
title_full | [1,4-Bis(diphenylphosphanyl)butane-κ(2)
P,P′]dibromidopalladium(II) |
title_fullStr | [1,4-Bis(diphenylphosphanyl)butane-κ(2)
P,P′]dibromidopalladium(II) |
title_full_unstemmed | [1,4-Bis(diphenylphosphanyl)butane-κ(2)
P,P′]dibromidopalladium(II) |
title_short | [1,4-Bis(diphenylphosphanyl)butane-κ(2)
P,P′]dibromidopalladium(II) |
title_sort | [1,4-bis(diphenylphosphanyl)butane-κ(2)
p,p′]dibromidopalladium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998252/ https://www.ncbi.nlm.nih.gov/pubmed/24764813 http://dx.doi.org/10.1107/S1600536814000774 |
work_keys_str_mv | AT hakwang 14bisdiphenylphosphanylbutanek2ppdibromidopalladiumii AT songyosoon 14bisdiphenylphosphanylbutanek2ppdibromidopalladiumii |