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[1,4-Bis(di­phenyl­phosphan­yl)butane-κ(2) P,P′]di­bromido­palladium(II)

In the title complex, [PdBr(2)(C(28)H(28)P(2))], the Pd(II) ion has a distorted cis-Br(2)P(2) square-planar coordination geometry defined by two P atoms from the chelating 1,4-bis­(di­phenyl­phosphan­yl)butane ligand and two Br(−) anions. The four phenyl rings are inclined to the least-squares plane...

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Autores principales: Ha, Kwang, Song, Yo Soon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998252/
https://www.ncbi.nlm.nih.gov/pubmed/24764813
http://dx.doi.org/10.1107/S1600536814000774
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author Ha, Kwang
Song, Yo Soon
author_facet Ha, Kwang
Song, Yo Soon
author_sort Ha, Kwang
collection PubMed
description In the title complex, [PdBr(2)(C(28)H(28)P(2))], the Pd(II) ion has a distorted cis-Br(2)P(2) square-planar coordination geometry defined by two P atoms from the chelating 1,4-bis­(di­phenyl­phosphan­yl)butane ligand and two Br(−) anions. The four phenyl rings are inclined to the least-squares plane of the PdBr(2)P(2) unit [maximum deviation = 0.1294 (7) Å], making dihedral angles of 66.3 (2), 87.2 (2), 68.8 (2) and 86.8 (2)°. The butyl­ene chain is in a gauche conformation, with a C—C—C—C torsion angle of 57.0 (8)°. Inter­molecular C—H⋯Br hydrogen bonds link the complex mol­ecules into supra­molecular layers in the ab plane. Weak π–π inter­actions, both intra- and inter­molecular [shortest inter-centroid distance = 4.598 (5) Å], are also noted in the three-dimensional architecture.
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spelling pubmed-39982522014-04-24 [1,4-Bis(di­phenyl­phosphan­yl)butane-κ(2) P,P′]di­bromido­palladium(II) Ha, Kwang Song, Yo Soon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PdBr(2)(C(28)H(28)P(2))], the Pd(II) ion has a distorted cis-Br(2)P(2) square-planar coordination geometry defined by two P atoms from the chelating 1,4-bis­(di­phenyl­phosphan­yl)butane ligand and two Br(−) anions. The four phenyl rings are inclined to the least-squares plane of the PdBr(2)P(2) unit [maximum deviation = 0.1294 (7) Å], making dihedral angles of 66.3 (2), 87.2 (2), 68.8 (2) and 86.8 (2)°. The butyl­ene chain is in a gauche conformation, with a C—C—C—C torsion angle of 57.0 (8)°. Inter­molecular C—H⋯Br hydrogen bonds link the complex mol­ecules into supra­molecular layers in the ab plane. Weak π–π inter­actions, both intra- and inter­molecular [shortest inter-centroid distance = 4.598 (5) Å], are also noted in the three-dimensional architecture. International Union of Crystallography 2014-01-18 /pmc/articles/PMC3998252/ /pubmed/24764813 http://dx.doi.org/10.1107/S1600536814000774 Text en © Ha and Song 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Song, Yo Soon
[1,4-Bis(di­phenyl­phosphan­yl)butane-κ(2) P,P′]di­bromido­palladium(II)
title [1,4-Bis(di­phenyl­phosphan­yl)butane-κ(2) P,P′]di­bromido­palladium(II)
title_full [1,4-Bis(di­phenyl­phosphan­yl)butane-κ(2) P,P′]di­bromido­palladium(II)
title_fullStr [1,4-Bis(di­phenyl­phosphan­yl)butane-κ(2) P,P′]di­bromido­palladium(II)
title_full_unstemmed [1,4-Bis(di­phenyl­phosphan­yl)butane-κ(2) P,P′]di­bromido­palladium(II)
title_short [1,4-Bis(di­phenyl­phosphan­yl)butane-κ(2) P,P′]di­bromido­palladium(II)
title_sort [1,4-bis(di­phenyl­phosphan­yl)butane-κ(2) p,p′]di­bromido­palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998252/
https://www.ncbi.nlm.nih.gov/pubmed/24764813
http://dx.doi.org/10.1107/S1600536814000774
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