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cis-Tri­aqua­[1,1′-(propane-1,3-di­yl)bis­(pyridin-1-ium-4-carboxyl­ato)-κO]bis­(thio­cyanato-κN)manganese(II) dihydrate

In the title compound, [Mn(NCS)(2)(C(15)H(14)N(2)O(4))(H(2)O)(3)]·2H(2)O, the metal ion is octa­hedrally coordinated by three water mol­ecules, one carboxyl­ate O atom from a 1,1′-(propane-1,3-di­yl)bis­(pyridinium-4-carboxyl­ate) ligand and two N atoms from two thio­cyanate anions in cis positions,...

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Detalles Bibliográficos
Autores principales: Tan, Qing-Hua, Wang, Yan-Qin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998253/
https://www.ncbi.nlm.nih.gov/pubmed/24764814
http://dx.doi.org/10.1107/S1600536814000701
Descripción
Sumario:In the title compound, [Mn(NCS)(2)(C(15)H(14)N(2)O(4))(H(2)O)(3)]·2H(2)O, the metal ion is octa­hedrally coordinated by three water mol­ecules, one carboxyl­ate O atom from a 1,1′-(propane-1,3-di­yl)bis­(pyridinium-4-carboxyl­ate) ligand and two N atoms from two thio­cyanate anions in cis positions, forming a mononuclear complex mol­ecule. In the crystal, mol­ecules are connected into a three-dimensional architecture through O—H⋯O hydrogen bonds involving water mol­ecules and carboxyl­ate groups.