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cis-Triaqua[1,1′-(propane-1,3-diyl)bis(pyridin-1-ium-4-carboxylato)-κO]bis(thiocyanato-κN)manganese(II) dihydrate
In the title compound, [Mn(NCS)(2)(C(15)H(14)N(2)O(4))(H(2)O)(3)]·2H(2)O, the metal ion is octahedrally coordinated by three water molecules, one carboxylate O atom from a 1,1′-(propane-1,3-diyl)bis(pyridinium-4-carboxylate) ligand and two N atoms from two thiocyanate anions in cis positions,...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998253/ https://www.ncbi.nlm.nih.gov/pubmed/24764814 http://dx.doi.org/10.1107/S1600536814000701 |
Sumario: | In the title compound, [Mn(NCS)(2)(C(15)H(14)N(2)O(4))(H(2)O)(3)]·2H(2)O, the metal ion is octahedrally coordinated by three water molecules, one carboxylate O atom from a 1,1′-(propane-1,3-diyl)bis(pyridinium-4-carboxylate) ligand and two N atoms from two thiocyanate anions in cis positions, forming a mononuclear complex molecule. In the crystal, molecules are connected into a three-dimensional architecture through O—H⋯O hydrogen bonds involving water molecules and carboxylate groups. |
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