cis-Tri­aqua­[1,1′-(propane-1,3-di­yl)bis­(pyridin-1-ium-4-carboxyl­ato)-κO]bis­(thio­cyanato-κN)manganese(II) dihydrate

In the title compound, [Mn(NCS)(2)(C(15)H(14)N(2)O(4))(H(2)O)(3)]·2H(2)O, the metal ion is octa­hedrally coordinated by three water mol­ecules, one carboxyl­ate O atom from a 1,1′-(propane-1,3-di­yl)bis­(pyridinium-4-carboxyl­ate) ligand and two N atoms from two thio­cyanate anions in cis positions,...

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Detalles Bibliográficos
Autores principales: Tan, Qing-Hua, Wang, Yan-Qin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998253/
https://www.ncbi.nlm.nih.gov/pubmed/24764814
http://dx.doi.org/10.1107/S1600536814000701
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author Tan, Qing-Hua
Wang, Yan-Qin
author_facet Tan, Qing-Hua
Wang, Yan-Qin
author_sort Tan, Qing-Hua
collection PubMed
description In the title compound, [Mn(NCS)(2)(C(15)H(14)N(2)O(4))(H(2)O)(3)]·2H(2)O, the metal ion is octa­hedrally coordinated by three water mol­ecules, one carboxyl­ate O atom from a 1,1′-(propane-1,3-di­yl)bis­(pyridinium-4-carboxyl­ate) ligand and two N atoms from two thio­cyanate anions in cis positions, forming a mononuclear complex mol­ecule. In the crystal, mol­ecules are connected into a three-dimensional architecture through O—H⋯O hydrogen bonds involving water mol­ecules and carboxyl­ate groups.
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spelling pubmed-39982532014-04-24 cis-Tri­aqua­[1,1′-(propane-1,3-di­yl)bis­(pyridin-1-ium-4-carboxyl­ato)-κO]bis­(thio­cyanato-κN)manganese(II) dihydrate Tan, Qing-Hua Wang, Yan-Qin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(NCS)(2)(C(15)H(14)N(2)O(4))(H(2)O)(3)]·2H(2)O, the metal ion is octa­hedrally coordinated by three water mol­ecules, one carboxyl­ate O atom from a 1,1′-(propane-1,3-di­yl)bis­(pyridinium-4-carboxyl­ate) ligand and two N atoms from two thio­cyanate anions in cis positions, forming a mononuclear complex mol­ecule. In the crystal, mol­ecules are connected into a three-dimensional architecture through O—H⋯O hydrogen bonds involving water mol­ecules and carboxyl­ate groups. International Union of Crystallography 2014-01-18 /pmc/articles/PMC3998253/ /pubmed/24764814 http://dx.doi.org/10.1107/S1600536814000701 Text en © Tan and Wang 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tan, Qing-Hua
Wang, Yan-Qin
cis-Tri­aqua­[1,1′-(propane-1,3-di­yl)bis­(pyridin-1-ium-4-carboxyl­ato)-κO]bis­(thio­cyanato-κN)manganese(II) dihydrate
title cis-Tri­aqua­[1,1′-(propane-1,3-di­yl)bis­(pyridin-1-ium-4-carboxyl­ato)-κO]bis­(thio­cyanato-κN)manganese(II) dihydrate
title_full cis-Tri­aqua­[1,1′-(propane-1,3-di­yl)bis­(pyridin-1-ium-4-carboxyl­ato)-κO]bis­(thio­cyanato-κN)manganese(II) dihydrate
title_fullStr cis-Tri­aqua­[1,1′-(propane-1,3-di­yl)bis­(pyridin-1-ium-4-carboxyl­ato)-κO]bis­(thio­cyanato-κN)manganese(II) dihydrate
title_full_unstemmed cis-Tri­aqua­[1,1′-(propane-1,3-di­yl)bis­(pyridin-1-ium-4-carboxyl­ato)-κO]bis­(thio­cyanato-κN)manganese(II) dihydrate
title_short cis-Tri­aqua­[1,1′-(propane-1,3-di­yl)bis­(pyridin-1-ium-4-carboxyl­ato)-κO]bis­(thio­cyanato-κN)manganese(II) dihydrate
title_sort cis-tri­aqua­[1,1′-(propane-1,3-di­yl)bis­(pyridin-1-ium-4-carboxyl­ato)-κo]bis­(thio­cyanato-κn)manganese(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998253/
https://www.ncbi.nlm.nih.gov/pubmed/24764814
http://dx.doi.org/10.1107/S1600536814000701
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AT wangyanqin cistriaqua11propane13diylbispyridin1ium4carboxylatokobisthiocyanatoknmanganeseiidihydrate

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