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Tetra­kis(di­propyl­ammonium) tetra­kis(oxa­lato-κ(2) O (1),O (2))stannate(IV) mono­hydrate: a complex with an eight-coordinate Sn(IV) atom

In the title salt, [(CH(3)CH(2)CH(2))(2)NH(2)](4)[Sn(C(2)O(4))(4)]·H(2)O, the Sn(IV) atom of the stannate anion is located on a special position with -42m symmetry. It is eight-coordinated by four chelating oxalate anions. The di­propyl­ammonium cation possesses mirror symmetry while the lattice wat...

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Autores principales: Gueye, Ndongo, Diop, Libasse, Stoeckli-Evans, Helen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998257/
https://www.ncbi.nlm.nih.gov/pubmed/24764818
http://dx.doi.org/10.1107/S160053681303496X
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author Gueye, Ndongo
Diop, Libasse
Stoeckli-Evans, Helen
author_facet Gueye, Ndongo
Diop, Libasse
Stoeckli-Evans, Helen
author_sort Gueye, Ndongo
collection PubMed
description In the title salt, [(CH(3)CH(2)CH(2))(2)NH(2)](4)[Sn(C(2)O(4))(4)]·H(2)O, the Sn(IV) atom of the stannate anion is located on a special position with -42m symmetry. It is eight-coordinated by four chelating oxalate anions. The di­propyl­ammonium cation possesses mirror symmetry while the lattice water mol­ecule is disordered about a position with -42m symmetry and has an occupancy of 0.25. In the crystal, the anions and cations are linked by N—H⋯O hydrogen bonds, forming a three-dimensional network. This network is futher stabilized by weak O—H⋯O hydrogen bonds involving the water mol­ecules and oxalate O atoms. The crystal studied was refined as an inversion twin.
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spelling pubmed-39982572014-04-24 Tetra­kis(di­propyl­ammonium) tetra­kis(oxa­lato-κ(2) O (1),O (2))stannate(IV) mono­hydrate: a complex with an eight-coordinate Sn(IV) atom Gueye, Ndongo Diop, Libasse Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [(CH(3)CH(2)CH(2))(2)NH(2)](4)[Sn(C(2)O(4))(4)]·H(2)O, the Sn(IV) atom of the stannate anion is located on a special position with -42m symmetry. It is eight-coordinated by four chelating oxalate anions. The di­propyl­ammonium cation possesses mirror symmetry while the lattice water mol­ecule is disordered about a position with -42m symmetry and has an occupancy of 0.25. In the crystal, the anions and cations are linked by N—H⋯O hydrogen bonds, forming a three-dimensional network. This network is futher stabilized by weak O—H⋯O hydrogen bonds involving the water mol­ecules and oxalate O atoms. The crystal studied was refined as an inversion twin. International Union of Crystallography 2014-01-18 /pmc/articles/PMC3998257/ /pubmed/24764818 http://dx.doi.org/10.1107/S160053681303496X Text en © Gueye et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gueye, Ndongo
Diop, Libasse
Stoeckli-Evans, Helen
Tetra­kis(di­propyl­ammonium) tetra­kis(oxa­lato-κ(2) O (1),O (2))stannate(IV) mono­hydrate: a complex with an eight-coordinate Sn(IV) atom
title Tetra­kis(di­propyl­ammonium) tetra­kis(oxa­lato-κ(2) O (1),O (2))stannate(IV) mono­hydrate: a complex with an eight-coordinate Sn(IV) atom
title_full Tetra­kis(di­propyl­ammonium) tetra­kis(oxa­lato-κ(2) O (1),O (2))stannate(IV) mono­hydrate: a complex with an eight-coordinate Sn(IV) atom
title_fullStr Tetra­kis(di­propyl­ammonium) tetra­kis(oxa­lato-κ(2) O (1),O (2))stannate(IV) mono­hydrate: a complex with an eight-coordinate Sn(IV) atom
title_full_unstemmed Tetra­kis(di­propyl­ammonium) tetra­kis(oxa­lato-κ(2) O (1),O (2))stannate(IV) mono­hydrate: a complex with an eight-coordinate Sn(IV) atom
title_short Tetra­kis(di­propyl­ammonium) tetra­kis(oxa­lato-κ(2) O (1),O (2))stannate(IV) mono­hydrate: a complex with an eight-coordinate Sn(IV) atom
title_sort tetra­kis(di­propyl­ammonium) tetra­kis(oxa­lato-κ(2) o (1),o (2))stannate(iv) mono­hydrate: a complex with an eight-coordinate sn(iv) atom
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998257/
https://www.ncbi.nlm.nih.gov/pubmed/24764818
http://dx.doi.org/10.1107/S160053681303496X
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