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Tetrakis(dipropylammonium) tetrakis(oxalato-κ(2) O (1),O (2))stannate(IV) monohydrate: a complex with an eight-coordinate Sn(IV) atom
In the title salt, [(CH(3)CH(2)CH(2))(2)NH(2)](4)[Sn(C(2)O(4))(4)]·H(2)O, the Sn(IV) atom of the stannate anion is located on a special position with -42m symmetry. It is eight-coordinated by four chelating oxalate anions. The dipropylammonium cation possesses mirror symmetry while the lattice wat...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998257/ https://www.ncbi.nlm.nih.gov/pubmed/24764818 http://dx.doi.org/10.1107/S160053681303496X |
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author | Gueye, Ndongo Diop, Libasse Stoeckli-Evans, Helen |
author_facet | Gueye, Ndongo Diop, Libasse Stoeckli-Evans, Helen |
author_sort | Gueye, Ndongo |
collection | PubMed |
description | In the title salt, [(CH(3)CH(2)CH(2))(2)NH(2)](4)[Sn(C(2)O(4))(4)]·H(2)O, the Sn(IV) atom of the stannate anion is located on a special position with -42m symmetry. It is eight-coordinated by four chelating oxalate anions. The dipropylammonium cation possesses mirror symmetry while the lattice water molecule is disordered about a position with -42m symmetry and has an occupancy of 0.25. In the crystal, the anions and cations are linked by N—H⋯O hydrogen bonds, forming a three-dimensional network. This network is futher stabilized by weak O—H⋯O hydrogen bonds involving the water molecules and oxalate O atoms. The crystal studied was refined as an inversion twin. |
format | Online Article Text |
id | pubmed-3998257 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39982572014-04-24 Tetrakis(dipropylammonium) tetrakis(oxalato-κ(2) O (1),O (2))stannate(IV) monohydrate: a complex with an eight-coordinate Sn(IV) atom Gueye, Ndongo Diop, Libasse Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [(CH(3)CH(2)CH(2))(2)NH(2)](4)[Sn(C(2)O(4))(4)]·H(2)O, the Sn(IV) atom of the stannate anion is located on a special position with -42m symmetry. It is eight-coordinated by four chelating oxalate anions. The dipropylammonium cation possesses mirror symmetry while the lattice water molecule is disordered about a position with -42m symmetry and has an occupancy of 0.25. In the crystal, the anions and cations are linked by N—H⋯O hydrogen bonds, forming a three-dimensional network. This network is futher stabilized by weak O—H⋯O hydrogen bonds involving the water molecules and oxalate O atoms. The crystal studied was refined as an inversion twin. International Union of Crystallography 2014-01-18 /pmc/articles/PMC3998257/ /pubmed/24764818 http://dx.doi.org/10.1107/S160053681303496X Text en © Gueye et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gueye, Ndongo Diop, Libasse Stoeckli-Evans, Helen Tetrakis(dipropylammonium) tetrakis(oxalato-κ(2) O (1),O (2))stannate(IV) monohydrate: a complex with an eight-coordinate Sn(IV) atom |
title | Tetrakis(dipropylammonium) tetrakis(oxalato-κ(2)
O
(1),O
(2))stannate(IV) monohydrate: a complex with an eight-coordinate Sn(IV) atom |
title_full | Tetrakis(dipropylammonium) tetrakis(oxalato-κ(2)
O
(1),O
(2))stannate(IV) monohydrate: a complex with an eight-coordinate Sn(IV) atom |
title_fullStr | Tetrakis(dipropylammonium) tetrakis(oxalato-κ(2)
O
(1),O
(2))stannate(IV) monohydrate: a complex with an eight-coordinate Sn(IV) atom |
title_full_unstemmed | Tetrakis(dipropylammonium) tetrakis(oxalato-κ(2)
O
(1),O
(2))stannate(IV) monohydrate: a complex with an eight-coordinate Sn(IV) atom |
title_short | Tetrakis(dipropylammonium) tetrakis(oxalato-κ(2)
O
(1),O
(2))stannate(IV) monohydrate: a complex with an eight-coordinate Sn(IV) atom |
title_sort | tetrakis(dipropylammonium) tetrakis(oxalato-κ(2)
o
(1),o
(2))stannate(iv) monohydrate: a complex with an eight-coordinate sn(iv) atom |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998257/ https://www.ncbi.nlm.nih.gov/pubmed/24764818 http://dx.doi.org/10.1107/S160053681303496X |
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