(1-Methyl-1H-imidazole-κN (3))(1-methyl-2-nitroso­benzene-κN)(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II) di­chloro­methane monosolvate

The solvated title compound, [Fe(C(44)H(28)N(4))(C(4)H(6)N(2))(C(7)H(7)NO)]·CH(2)Cl(2), is a porphyrin complex containing an octahedrally coordinated Fe(II) atom with 1-methylimidazole [Fe—N = 2.0651 (17) Å] and o-nitro­sotoluene ligands at the axial positions. The o-nitro­sotoluene ligand is N-boun...

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Autores principales: Abucayon, Erwin G., Awasabisah, Dennis, Powell, Douglas R., Richter-Addo, George B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998258/
https://www.ncbi.nlm.nih.gov/pubmed/24764819
http://dx.doi.org/10.1107/S160053681400083X
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author Abucayon, Erwin G.
Awasabisah, Dennis
Powell, Douglas R.
Richter-Addo, George B.
author_facet Abucayon, Erwin G.
Awasabisah, Dennis
Powell, Douglas R.
Richter-Addo, George B.
author_sort Abucayon, Erwin G.
collection PubMed
description The solvated title compound, [Fe(C(44)H(28)N(4))(C(4)H(6)N(2))(C(7)H(7)NO)]·CH(2)Cl(2), is a porphyrin complex containing an octahedrally coordinated Fe(II) atom with 1-methylimidazole [Fe—N = 2.0651 (17) Å] and o-nitro­sotoluene ligands at the axial positions. The o-nitro­sotoluene ligand is N-bound to iron(II) [Fe—N = 1.8406 (18)Å and Fe—N—O = 122.54 (14)°]. The axial N—Fe—N linkage is almost linear, with a bond angle of 177.15 (7)°. One phenyl group of the porphyrin ligand is disordered over two orientations in a 0.710 (3):0.290 (3) ratio. The di­chloro­methane solvent mol­ecule was severely disordered and its contribution to the scattering was removed with the SQUEEZE routine [van der Sluis & Spek (1990 ▶). Acta Cryst. A46, 194–201].
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spelling pubmed-39982582014-04-24 (1-Methyl-1H-imidazole-κN (3))(1-methyl-2-nitroso­benzene-κN)(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II) di­chloro­methane monosolvate Abucayon, Erwin G. Awasabisah, Dennis Powell, Douglas R. Richter-Addo, George B. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The solvated title compound, [Fe(C(44)H(28)N(4))(C(4)H(6)N(2))(C(7)H(7)NO)]·CH(2)Cl(2), is a porphyrin complex containing an octahedrally coordinated Fe(II) atom with 1-methylimidazole [Fe—N = 2.0651 (17) Å] and o-nitro­sotoluene ligands at the axial positions. The o-nitro­sotoluene ligand is N-bound to iron(II) [Fe—N = 1.8406 (18)Å and Fe—N—O = 122.54 (14)°]. The axial N—Fe—N linkage is almost linear, with a bond angle of 177.15 (7)°. One phenyl group of the porphyrin ligand is disordered over two orientations in a 0.710 (3):0.290 (3) ratio. The di­chloro­methane solvent mol­ecule was severely disordered and its contribution to the scattering was removed with the SQUEEZE routine [van der Sluis & Spek (1990 ▶). Acta Cryst. A46, 194–201]. International Union of Crystallography 2014-01-18 /pmc/articles/PMC3998258/ /pubmed/24764819 http://dx.doi.org/10.1107/S160053681400083X Text en © Abucayon et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Abucayon, Erwin G.
Awasabisah, Dennis
Powell, Douglas R.
Richter-Addo, George B.
(1-Methyl-1H-imidazole-κN (3))(1-methyl-2-nitroso­benzene-κN)(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II) di­chloro­methane monosolvate
title (1-Methyl-1H-imidazole-κN (3))(1-methyl-2-nitroso­benzene-κN)(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II) di­chloro­methane monosolvate
title_full (1-Methyl-1H-imidazole-κN (3))(1-methyl-2-nitroso­benzene-κN)(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II) di­chloro­methane monosolvate
title_fullStr (1-Methyl-1H-imidazole-κN (3))(1-methyl-2-nitroso­benzene-κN)(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II) di­chloro­methane monosolvate
title_full_unstemmed (1-Methyl-1H-imidazole-κN (3))(1-methyl-2-nitroso­benzene-κN)(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II) di­chloro­methane monosolvate
title_short (1-Methyl-1H-imidazole-κN (3))(1-methyl-2-nitroso­benzene-κN)(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)iron(II) di­chloro­methane monosolvate
title_sort (1-methyl-1h-imidazole-κn (3))(1-methyl-2-nitroso­benzene-κn)(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) n)iron(ii) di­chloro­methane monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998258/
https://www.ncbi.nlm.nih.gov/pubmed/24764819
http://dx.doi.org/10.1107/S160053681400083X
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