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Bis(1,10-phenanthrolin-1-ium) tetrachloridozincate monohydrate
In the crystal structure of the title compound, (C(12)H(9)N(2))(2)[ZnCl(4)]·H(2)O, the two independent 1,10-phenanthrolinium cations are bridged by the water molecule and the tetrahedral tetrachloridozincate anion via N—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds, forming chains along [100]. The chains a...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998259/ https://www.ncbi.nlm.nih.gov/pubmed/24764820 http://dx.doi.org/10.1107/S1600536814000208 |
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author | Govindan, E. Thirumurugan, Subramani Ganeshraja, Ayyakannu Sundaram Anbalagan, Krishnamoorthy SubbiahPandi, A. |
author_facet | Govindan, E. Thirumurugan, Subramani Ganeshraja, Ayyakannu Sundaram Anbalagan, Krishnamoorthy SubbiahPandi, A. |
author_sort | Govindan, E. |
collection | PubMed |
description | In the crystal structure of the title compound, (C(12)H(9)N(2))(2)[ZnCl(4)]·H(2)O, the two independent 1,10-phenanthrolinium cations are bridged by the water molecule and the tetrahedral tetrachloridozincate anion via N—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds, forming chains along [100]. The chains are linked via C—H⋯Cl hydrogen bonds and a number of π–π interactions [centroid–centroid distances vary from 3.5594 (14) to 3.7057 (13) Å], forming a three-dimensional network. In each 1,10-phenanthrolinium cation, there is a short N—H⋯N interaction. |
format | Online Article Text |
id | pubmed-3998259 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39982592014-04-24 Bis(1,10-phenanthrolin-1-ium) tetrachloridozincate monohydrate Govindan, E. Thirumurugan, Subramani Ganeshraja, Ayyakannu Sundaram Anbalagan, Krishnamoorthy SubbiahPandi, A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, (C(12)H(9)N(2))(2)[ZnCl(4)]·H(2)O, the two independent 1,10-phenanthrolinium cations are bridged by the water molecule and the tetrahedral tetrachloridozincate anion via N—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds, forming chains along [100]. The chains are linked via C—H⋯Cl hydrogen bonds and a number of π–π interactions [centroid–centroid distances vary from 3.5594 (14) to 3.7057 (13) Å], forming a three-dimensional network. In each 1,10-phenanthrolinium cation, there is a short N—H⋯N interaction. International Union of Crystallography 2014-01-18 /pmc/articles/PMC3998259/ /pubmed/24764820 http://dx.doi.org/10.1107/S1600536814000208 Text en © Govindan et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Govindan, E. Thirumurugan, Subramani Ganeshraja, Ayyakannu Sundaram Anbalagan, Krishnamoorthy SubbiahPandi, A. Bis(1,10-phenanthrolin-1-ium) tetrachloridozincate monohydrate |
title | Bis(1,10-phenanthrolin-1-ium) tetrachloridozincate monohydrate |
title_full | Bis(1,10-phenanthrolin-1-ium) tetrachloridozincate monohydrate |
title_fullStr | Bis(1,10-phenanthrolin-1-ium) tetrachloridozincate monohydrate |
title_full_unstemmed | Bis(1,10-phenanthrolin-1-ium) tetrachloridozincate monohydrate |
title_short | Bis(1,10-phenanthrolin-1-ium) tetrachloridozincate monohydrate |
title_sort | bis(1,10-phenanthrolin-1-ium) tetrachloridozincate monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998259/ https://www.ncbi.nlm.nih.gov/pubmed/24764820 http://dx.doi.org/10.1107/S1600536814000208 |
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