Cargando…

Bis(1,10-phenanthrolin-1-ium) tetra­chlorido­zincate monohydrate

In the crystal structure of the title compound, (C(12)H(9)N(2))(2)[ZnCl(4)]·H(2)O, the two independent 1,10-phenanthrolinium cations are bridged by the water mol­ecule and the tetrahedral tetrachloridozincate anion via N—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds, forming chains along [100]. The chains a...

Descripción completa

Detalles Bibliográficos
Autores principales: Govindan, E., Thirumurugan, Subramani, Ganeshraja, Ayyakannu Sundaram, Anbalagan, Krishnamoorthy, SubbiahPandi, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998259/
https://www.ncbi.nlm.nih.gov/pubmed/24764820
http://dx.doi.org/10.1107/S1600536814000208
_version_ 1782313322599677952
author Govindan, E.
Thirumurugan, Subramani
Ganeshraja, Ayyakannu Sundaram
Anbalagan, Krishnamoorthy
SubbiahPandi, A.
author_facet Govindan, E.
Thirumurugan, Subramani
Ganeshraja, Ayyakannu Sundaram
Anbalagan, Krishnamoorthy
SubbiahPandi, A.
author_sort Govindan, E.
collection PubMed
description In the crystal structure of the title compound, (C(12)H(9)N(2))(2)[ZnCl(4)]·H(2)O, the two independent 1,10-phenanthrolinium cations are bridged by the water mol­ecule and the tetrahedral tetrachloridozincate anion via N—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds, forming chains along [100]. The chains are linked via C—H⋯Cl hydrogen bonds and a number of π–π inter­actions [centroid–centroid distances vary from 3.5594 (14) to 3.7057 (13) Å], forming a three-dimensional network. In each 1,10-phenanthrolinium cation, there is a short N—H⋯N inter­action.
format Online
Article
Text
id pubmed-3998259
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-39982592014-04-24 Bis(1,10-phenanthrolin-1-ium) tetra­chlorido­zincate monohydrate Govindan, E. Thirumurugan, Subramani Ganeshraja, Ayyakannu Sundaram Anbalagan, Krishnamoorthy SubbiahPandi, A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, (C(12)H(9)N(2))(2)[ZnCl(4)]·H(2)O, the two independent 1,10-phenanthrolinium cations are bridged by the water mol­ecule and the tetrahedral tetrachloridozincate anion via N—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds, forming chains along [100]. The chains are linked via C—H⋯Cl hydrogen bonds and a number of π–π inter­actions [centroid–centroid distances vary from 3.5594 (14) to 3.7057 (13) Å], forming a three-dimensional network. In each 1,10-phenanthrolinium cation, there is a short N—H⋯N inter­action. International Union of Crystallography 2014-01-18 /pmc/articles/PMC3998259/ /pubmed/24764820 http://dx.doi.org/10.1107/S1600536814000208 Text en © Govindan et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Govindan, E.
Thirumurugan, Subramani
Ganeshraja, Ayyakannu Sundaram
Anbalagan, Krishnamoorthy
SubbiahPandi, A.
Bis(1,10-phenanthrolin-1-ium) tetra­chlorido­zincate monohydrate
title Bis(1,10-phenanthrolin-1-ium) tetra­chlorido­zincate monohydrate
title_full Bis(1,10-phenanthrolin-1-ium) tetra­chlorido­zincate monohydrate
title_fullStr Bis(1,10-phenanthrolin-1-ium) tetra­chlorido­zincate monohydrate
title_full_unstemmed Bis(1,10-phenanthrolin-1-ium) tetra­chlorido­zincate monohydrate
title_short Bis(1,10-phenanthrolin-1-ium) tetra­chlorido­zincate monohydrate
title_sort bis(1,10-phenanthrolin-1-ium) tetra­chlorido­zincate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998259/
https://www.ncbi.nlm.nih.gov/pubmed/24764820
http://dx.doi.org/10.1107/S1600536814000208
work_keys_str_mv AT govindane bis110phenanthrolin1iumtetrachloridozincatemonohydrate
AT thirumurugansubramani bis110phenanthrolin1iumtetrachloridozincatemonohydrate
AT ganeshrajaayyakannusundaram bis110phenanthrolin1iumtetrachloridozincatemonohydrate
AT anbalagankrishnamoorthy bis110phenanthrolin1iumtetrachloridozincatemonohydrate
AT subbiahpandia bis110phenanthrolin1iumtetrachloridozincatemonohydrate