Di-μ-tricyanido-tetra­cyanidobis[hydro­tris­(pyrazoylborato)]tetra­methanol­diiron(III)iron(II) di­methanol disolvate

In the title complex, [Fe(II)Fe(III) (2)(C(9)H(10)BN(6))(2)(CN)(6)(CH(3)OH)(4)]·2CH(3)OH, two [Fe(III)(Tp)(CN)(3)](−) anions [Tp is hydro­tris­(pyrazoylborate)] are bridged by an [Fe(II)(MeOH)(4)](2+) cation, forming a centrosymmetric trinuclear unit. These units are connected via O—H⋯O and O—H⋯N hy...

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Detalles Bibliográficos
Autores principales: Zhang, Kuirun, Sato, Osamu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998261/
https://www.ncbi.nlm.nih.gov/pubmed/24764822
http://dx.doi.org/10.1107/S1600536814001019
Descripción
Sumario:In the title complex, [Fe(II)Fe(III) (2)(C(9)H(10)BN(6))(2)(CN)(6)(CH(3)OH)(4)]·2CH(3)OH, two [Fe(III)(Tp)(CN)(3)](−) anions [Tp is hydro­tris­(pyrazoylborate)] are bridged by an [Fe(II)(MeOH)(4)](2+) cation, forming a centrosymmetric trinuclear unit. These units are connected via O—H⋯O and O—H⋯N hydrogen bonds involving the uncoordinated methanol solvent mol­ecules, forming a three-dimensional network.

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