Di-μ-tricyanido-tetra­cyanidobis[hydro­tris­(pyrazoylborato)]tetra­methanol­diiron(III)iron(II) di­methanol disolvate

In the title complex, [Fe(II)Fe(III) (2)(C(9)H(10)BN(6))(2)(CN)(6)(CH(3)OH)(4)]·2CH(3)OH, two [Fe(III)(Tp)(CN)(3)](−) anions [Tp is hydro­tris­(pyrazoylborate)] are bridged by an [Fe(II)(MeOH)(4)](2+) cation, forming a centrosymmetric trinuclear unit. These units are connected via O—H⋯O and O—H⋯N hy...

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Detalles Bibliográficos
Autores principales: Zhang, Kuirun, Sato, Osamu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998261/
https://www.ncbi.nlm.nih.gov/pubmed/24764822
http://dx.doi.org/10.1107/S1600536814001019
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author Zhang, Kuirun
Sato, Osamu
author_facet Zhang, Kuirun
Sato, Osamu
author_sort Zhang, Kuirun
collection PubMed
description In the title complex, [Fe(II)Fe(III) (2)(C(9)H(10)BN(6))(2)(CN)(6)(CH(3)OH)(4)]·2CH(3)OH, two [Fe(III)(Tp)(CN)(3)](−) anions [Tp is hydro­tris­(pyrazoylborate)] are bridged by an [Fe(II)(MeOH)(4)](2+) cation, forming a centrosymmetric trinuclear unit. These units are connected via O—H⋯O and O—H⋯N hydrogen bonds involving the uncoordinated methanol solvent mol­ecules, forming a three-dimensional network.
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spelling pubmed-39982612014-04-24 Di-μ-tricyanido-tetra­cyanidobis[hydro­tris­(pyrazoylborato)]tetra­methanol­diiron(III)iron(II) di­methanol disolvate Zhang, Kuirun Sato, Osamu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Fe(II)Fe(III) (2)(C(9)H(10)BN(6))(2)(CN)(6)(CH(3)OH)(4)]·2CH(3)OH, two [Fe(III)(Tp)(CN)(3)](−) anions [Tp is hydro­tris­(pyrazoylborate)] are bridged by an [Fe(II)(MeOH)(4)](2+) cation, forming a centrosymmetric trinuclear unit. These units are connected via O—H⋯O and O—H⋯N hydrogen bonds involving the uncoordinated methanol solvent mol­ecules, forming a three-dimensional network. International Union of Crystallography 2014-01-22 /pmc/articles/PMC3998261/ /pubmed/24764822 http://dx.doi.org/10.1107/S1600536814001019 Text en © Zhang and Sato 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Kuirun
Sato, Osamu
Di-μ-tricyanido-tetra­cyanidobis[hydro­tris­(pyrazoylborato)]tetra­methanol­diiron(III)iron(II) di­methanol disolvate
title Di-μ-tricyanido-tetra­cyanidobis[hydro­tris­(pyrazoylborato)]tetra­methanol­diiron(III)iron(II) di­methanol disolvate
title_full Di-μ-tricyanido-tetra­cyanidobis[hydro­tris­(pyrazoylborato)]tetra­methanol­diiron(III)iron(II) di­methanol disolvate
title_fullStr Di-μ-tricyanido-tetra­cyanidobis[hydro­tris­(pyrazoylborato)]tetra­methanol­diiron(III)iron(II) di­methanol disolvate
title_full_unstemmed Di-μ-tricyanido-tetra­cyanidobis[hydro­tris­(pyrazoylborato)]tetra­methanol­diiron(III)iron(II) di­methanol disolvate
title_short Di-μ-tricyanido-tetra­cyanidobis[hydro­tris­(pyrazoylborato)]tetra­methanol­diiron(III)iron(II) di­methanol disolvate
title_sort di-μ-tricyanido-tetra­cyanidobis[hydro­tris­(pyrazoylborato)]tetra­methanol­diiron(iii)iron(ii) di­methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998261/
https://www.ncbi.nlm.nih.gov/pubmed/24764822
http://dx.doi.org/10.1107/S1600536814001019
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AT satoosamu dimtricyanidotetracyanidobishydrotrispyrazoylboratotetramethanoldiironiiiironiidimethanoldisolvate

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