(Cyanido-κC)(2,2-di­phenyl­acetamido-κ(2) N,O)bis­(η(5)-penta­methyl­cyclo­penta­dien­yl)zirconium(IV)

In the title compound, [Zr(C(10)H(15))(2)(C(14)H(12)NO)(CN)], the Zr(IV) atom is coordinated by two penta­methyl­cyclo­penta­dienyl ligands, the amidate ligand via the N and O atoms, and an additional C N ligand. The four-membered metallacycle is nearly planar (r.m.s. deviation = 0.008 Å). In the cr...

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Detalles Bibliográficos
Autores principales: Becker, Lisanne, Spannenberg, Anke, Arndt, Perdita, Rosenthal, Uwe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998262/
https://www.ncbi.nlm.nih.gov/pubmed/24764823
http://dx.doi.org/10.1107/S1600536814001160
Descripción
Sumario:In the title compound, [Zr(C(10)H(15))(2)(C(14)H(12)NO)(CN)], the Zr(IV) atom is coordinated by two penta­methyl­cyclo­penta­dienyl ligands, the amidate ligand via the N and O atoms, and an additional C N ligand. The four-membered metallacycle is nearly planar (r.m.s. deviation = 0.008 Å). In the crystal, the mol­ecules are connected into centrosymmetric dimers via pairs of N—H⋯N hydrogen bonds.

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