(Cyanido-κC)(2,2-di­phenyl­acetamido-κ(2) N,O)bis­(η(5)-penta­methyl­cyclo­penta­dien­yl)zirconium(IV)

In the title compound, [Zr(C(10)H(15))(2)(C(14)H(12)NO)(CN)], the Zr(IV) atom is coordinated by two penta­methyl­cyclo­penta­dienyl ligands, the amidate ligand via the N and O atoms, and an additional C N ligand. The four-membered metallacycle is nearly planar (r.m.s. deviation = 0.008 Å). In the cr...

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Detalles Bibliográficos
Autores principales: Becker, Lisanne, Spannenberg, Anke, Arndt, Perdita, Rosenthal, Uwe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998262/
https://www.ncbi.nlm.nih.gov/pubmed/24764823
http://dx.doi.org/10.1107/S1600536814001160
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author Becker, Lisanne
Spannenberg, Anke
Arndt, Perdita
Rosenthal, Uwe
author_facet Becker, Lisanne
Spannenberg, Anke
Arndt, Perdita
Rosenthal, Uwe
author_sort Becker, Lisanne
collection PubMed
description In the title compound, [Zr(C(10)H(15))(2)(C(14)H(12)NO)(CN)], the Zr(IV) atom is coordinated by two penta­methyl­cyclo­penta­dienyl ligands, the amidate ligand via the N and O atoms, and an additional C N ligand. The four-membered metallacycle is nearly planar (r.m.s. deviation = 0.008 Å). In the crystal, the mol­ecules are connected into centrosymmetric dimers via pairs of N—H⋯N hydrogen bonds.
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spelling pubmed-39982622014-04-24 (Cyanido-κC)(2,2-di­phenyl­acetamido-κ(2) N,O)bis­(η(5)-penta­methyl­cyclo­penta­dien­yl)zirconium(IV) Becker, Lisanne Spannenberg, Anke Arndt, Perdita Rosenthal, Uwe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zr(C(10)H(15))(2)(C(14)H(12)NO)(CN)], the Zr(IV) atom is coordinated by two penta­methyl­cyclo­penta­dienyl ligands, the amidate ligand via the N and O atoms, and an additional C N ligand. The four-membered metallacycle is nearly planar (r.m.s. deviation = 0.008 Å). In the crystal, the mol­ecules are connected into centrosymmetric dimers via pairs of N—H⋯N hydrogen bonds. International Union of Crystallography 2014-01-22 /pmc/articles/PMC3998262/ /pubmed/24764823 http://dx.doi.org/10.1107/S1600536814001160 Text en © Becker et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Becker, Lisanne
Spannenberg, Anke
Arndt, Perdita
Rosenthal, Uwe
(Cyanido-κC)(2,2-di­phenyl­acetamido-κ(2) N,O)bis­(η(5)-penta­methyl­cyclo­penta­dien­yl)zirconium(IV)
title (Cyanido-κC)(2,2-di­phenyl­acetamido-κ(2) N,O)bis­(η(5)-penta­methyl­cyclo­penta­dien­yl)zirconium(IV)
title_full (Cyanido-κC)(2,2-di­phenyl­acetamido-κ(2) N,O)bis­(η(5)-penta­methyl­cyclo­penta­dien­yl)zirconium(IV)
title_fullStr (Cyanido-κC)(2,2-di­phenyl­acetamido-κ(2) N,O)bis­(η(5)-penta­methyl­cyclo­penta­dien­yl)zirconium(IV)
title_full_unstemmed (Cyanido-κC)(2,2-di­phenyl­acetamido-κ(2) N,O)bis­(η(5)-penta­methyl­cyclo­penta­dien­yl)zirconium(IV)
title_short (Cyanido-κC)(2,2-di­phenyl­acetamido-κ(2) N,O)bis­(η(5)-penta­methyl­cyclo­penta­dien­yl)zirconium(IV)
title_sort (cyanido-κc)(2,2-di­phenyl­acetamido-κ(2) n,o)bis­(η(5)-penta­methyl­cyclo­penta­dien­yl)zirconium(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998262/
https://www.ncbi.nlm.nih.gov/pubmed/24764823
http://dx.doi.org/10.1107/S1600536814001160
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AT arndtperdita cyanidokc22diphenylacetamidok2nobisē5pentamethylcyclopentadienylzirconiumiv
AT rosenthaluwe cyanidokc22diphenylacetamidok2nobisē5pentamethylcyclopentadienylzirconiumiv

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