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Chlorido[5-meth­oxy-1H-benzimidazole-2(3H)-thione-κS]bis­(tri­phenyl­phos­phane-κP)copper(I) methanol disolvate

In the title complex, [CuCl(C(8)H(8)N(2)OS)(C(18)H(15)P)(2)]·2CH(3)OH, the Cu(I) ion is coordinated by one chloride anion, one S atom from the 5-meth­oxy-1H-benzimidazole-2(3H)-thione ligand and two P atoms from two tri­phenyl­phosphine ligands in a distorted tetra­hedral geometry. One of the N-boun...

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Detalles Bibliográficos
Autor principal: Meng, Qing-Xuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998264/
https://www.ncbi.nlm.nih.gov/pubmed/24764825
http://dx.doi.org/10.1107/S1600536814001251
Descripción
Sumario:In the title complex, [CuCl(C(8)H(8)N(2)OS)(C(18)H(15)P)(2)]·2CH(3)OH, the Cu(I) ion is coordinated by one chloride anion, one S atom from the 5-meth­oxy-1H-benzimidazole-2(3H)-thione ligand and two P atoms from two tri­phenyl­phosphine ligands in a distorted tetra­hedral geometry. One of the N-bound H atoms is involved in an intra­molecular N—H⋯Cl hydrogen bond, while another one inter­acts with the solvent methanol mol­ecule via an N—H⋯O hydrogen bond. Inter­molecular O—H⋯Cl and O—H⋯O hydrogen bonds link two further complex mol­ecules and four solvent mol­ecules into a centrosymmetric structural unit. The short distance of 3.624 (4) Å between the centroids of the five- and the six-membered rings of two benzimidazole fragments indicates the presence of π–π inter­actions.