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Chlorido[5-methoxy-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol disolvate
In the title complex, [CuCl(C(8)H(8)N(2)OS)(C(18)H(15)P)(2)]·2CH(3)OH, the Cu(I) ion is coordinated by one chloride anion, one S atom from the 5-methoxy-1H-benzimidazole-2(3H)-thione ligand and two P atoms from two triphenylphosphine ligands in a distorted tetrahedral geometry. One of the N-boun...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998264/ https://www.ncbi.nlm.nih.gov/pubmed/24764825 http://dx.doi.org/10.1107/S1600536814001251 |
Sumario: | In the title complex, [CuCl(C(8)H(8)N(2)OS)(C(18)H(15)P)(2)]·2CH(3)OH, the Cu(I) ion is coordinated by one chloride anion, one S atom from the 5-methoxy-1H-benzimidazole-2(3H)-thione ligand and two P atoms from two triphenylphosphine ligands in a distorted tetrahedral geometry. One of the N-bound H atoms is involved in an intramolecular N—H⋯Cl hydrogen bond, while another one interacts with the solvent methanol molecule via an N—H⋯O hydrogen bond. Intermolecular O—H⋯Cl and O—H⋯O hydrogen bonds link two further complex molecules and four solvent molecules into a centrosymmetric structural unit. The short distance of 3.624 (4) Å between the centroids of the five- and the six-membered rings of two benzimidazole fragments indicates the presence of π–π interactions. |
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