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Chlorido[5-methoxy-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol disolvate
In the title complex, [CuCl(C(8)H(8)N(2)OS)(C(18)H(15)P)(2)]·2CH(3)OH, the Cu(I) ion is coordinated by one chloride anion, one S atom from the 5-methoxy-1H-benzimidazole-2(3H)-thione ligand and two P atoms from two triphenylphosphine ligands in a distorted tetrahedral geometry. One of the N-boun...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998264/ https://www.ncbi.nlm.nih.gov/pubmed/24764825 http://dx.doi.org/10.1107/S1600536814001251 |
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author | Meng, Qing-Xuan |
author_facet | Meng, Qing-Xuan |
author_sort | Meng, Qing-Xuan |
collection | PubMed |
description | In the title complex, [CuCl(C(8)H(8)N(2)OS)(C(18)H(15)P)(2)]·2CH(3)OH, the Cu(I) ion is coordinated by one chloride anion, one S atom from the 5-methoxy-1H-benzimidazole-2(3H)-thione ligand and two P atoms from two triphenylphosphine ligands in a distorted tetrahedral geometry. One of the N-bound H atoms is involved in an intramolecular N—H⋯Cl hydrogen bond, while another one interacts with the solvent methanol molecule via an N—H⋯O hydrogen bond. Intermolecular O—H⋯Cl and O—H⋯O hydrogen bonds link two further complex molecules and four solvent molecules into a centrosymmetric structural unit. The short distance of 3.624 (4) Å between the centroids of the five- and the six-membered rings of two benzimidazole fragments indicates the presence of π–π interactions. |
format | Online Article Text |
id | pubmed-3998264 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39982642014-04-24 Chlorido[5-methoxy-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol disolvate Meng, Qing-Xuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuCl(C(8)H(8)N(2)OS)(C(18)H(15)P)(2)]·2CH(3)OH, the Cu(I) ion is coordinated by one chloride anion, one S atom from the 5-methoxy-1H-benzimidazole-2(3H)-thione ligand and two P atoms from two triphenylphosphine ligands in a distorted tetrahedral geometry. One of the N-bound H atoms is involved in an intramolecular N—H⋯Cl hydrogen bond, while another one interacts with the solvent methanol molecule via an N—H⋯O hydrogen bond. Intermolecular O—H⋯Cl and O—H⋯O hydrogen bonds link two further complex molecules and four solvent molecules into a centrosymmetric structural unit. The short distance of 3.624 (4) Å between the centroids of the five- and the six-membered rings of two benzimidazole fragments indicates the presence of π–π interactions. International Union of Crystallography 2014-01-22 /pmc/articles/PMC3998264/ /pubmed/24764825 http://dx.doi.org/10.1107/S1600536814001251 Text en © Qing-Xuan Meng 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Meng, Qing-Xuan Chlorido[5-methoxy-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol disolvate |
title | Chlorido[5-methoxy-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol disolvate |
title_full | Chlorido[5-methoxy-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol disolvate |
title_fullStr | Chlorido[5-methoxy-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol disolvate |
title_full_unstemmed | Chlorido[5-methoxy-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol disolvate |
title_short | Chlorido[5-methoxy-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol disolvate |
title_sort | chlorido[5-methoxy-1h-benzimidazole-2(3h)-thione-κs]bis(triphenylphosphane-κp)copper(i) methanol disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998264/ https://www.ncbi.nlm.nih.gov/pubmed/24764825 http://dx.doi.org/10.1107/S1600536814001251 |
work_keys_str_mv | AT mengqingxuan chlorido5methoxy1hbenzimidazole23hthioneksbistriphenylphosphanekpcopperimethanoldisolvate |