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Chlorido[5-meth­oxy-1H-benzimidazole-2(3H)-thione-κS]bis­(tri­phenyl­phos­phane-κP)copper(I) methanol disolvate

In the title complex, [CuCl(C(8)H(8)N(2)OS)(C(18)H(15)P)(2)]·2CH(3)OH, the Cu(I) ion is coordinated by one chloride anion, one S atom from the 5-meth­oxy-1H-benzimidazole-2(3H)-thione ligand and two P atoms from two tri­phenyl­phosphine ligands in a distorted tetra­hedral geometry. One of the N-boun...

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Autor principal: Meng, Qing-Xuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998264/
https://www.ncbi.nlm.nih.gov/pubmed/24764825
http://dx.doi.org/10.1107/S1600536814001251
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author Meng, Qing-Xuan
author_facet Meng, Qing-Xuan
author_sort Meng, Qing-Xuan
collection PubMed
description In the title complex, [CuCl(C(8)H(8)N(2)OS)(C(18)H(15)P)(2)]·2CH(3)OH, the Cu(I) ion is coordinated by one chloride anion, one S atom from the 5-meth­oxy-1H-benzimidazole-2(3H)-thione ligand and two P atoms from two tri­phenyl­phosphine ligands in a distorted tetra­hedral geometry. One of the N-bound H atoms is involved in an intra­molecular N—H⋯Cl hydrogen bond, while another one inter­acts with the solvent methanol mol­ecule via an N—H⋯O hydrogen bond. Inter­molecular O—H⋯Cl and O—H⋯O hydrogen bonds link two further complex mol­ecules and four solvent mol­ecules into a centrosymmetric structural unit. The short distance of 3.624 (4) Å between the centroids of the five- and the six-membered rings of two benzimidazole fragments indicates the presence of π–π inter­actions.
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spelling pubmed-39982642014-04-24 Chlorido[5-meth­oxy-1H-benzimidazole-2(3H)-thione-κS]bis­(tri­phenyl­phos­phane-κP)copper(I) methanol disolvate Meng, Qing-Xuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuCl(C(8)H(8)N(2)OS)(C(18)H(15)P)(2)]·2CH(3)OH, the Cu(I) ion is coordinated by one chloride anion, one S atom from the 5-meth­oxy-1H-benzimidazole-2(3H)-thione ligand and two P atoms from two tri­phenyl­phosphine ligands in a distorted tetra­hedral geometry. One of the N-bound H atoms is involved in an intra­molecular N—H⋯Cl hydrogen bond, while another one inter­acts with the solvent methanol mol­ecule via an N—H⋯O hydrogen bond. Inter­molecular O—H⋯Cl and O—H⋯O hydrogen bonds link two further complex mol­ecules and four solvent mol­ecules into a centrosymmetric structural unit. The short distance of 3.624 (4) Å between the centroids of the five- and the six-membered rings of two benzimidazole fragments indicates the presence of π–π inter­actions. International Union of Crystallography 2014-01-22 /pmc/articles/PMC3998264/ /pubmed/24764825 http://dx.doi.org/10.1107/S1600536814001251 Text en © Qing-Xuan Meng 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meng, Qing-Xuan
Chlorido[5-meth­oxy-1H-benzimidazole-2(3H)-thione-κS]bis­(tri­phenyl­phos­phane-κP)copper(I) methanol disolvate
title Chlorido[5-meth­oxy-1H-benzimidazole-2(3H)-thione-κS]bis­(tri­phenyl­phos­phane-κP)copper(I) methanol disolvate
title_full Chlorido[5-meth­oxy-1H-benzimidazole-2(3H)-thione-κS]bis­(tri­phenyl­phos­phane-κP)copper(I) methanol disolvate
title_fullStr Chlorido[5-meth­oxy-1H-benzimidazole-2(3H)-thione-κS]bis­(tri­phenyl­phos­phane-κP)copper(I) methanol disolvate
title_full_unstemmed Chlorido[5-meth­oxy-1H-benzimidazole-2(3H)-thione-κS]bis­(tri­phenyl­phos­phane-κP)copper(I) methanol disolvate
title_short Chlorido[5-meth­oxy-1H-benzimidazole-2(3H)-thione-κS]bis­(tri­phenyl­phos­phane-κP)copper(I) methanol disolvate
title_sort chlorido[5-meth­oxy-1h-benzimidazole-2(3h)-thione-κs]bis­(tri­phenyl­phos­phane-κp)copper(i) methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998264/
https://www.ncbi.nlm.nih.gov/pubmed/24764825
http://dx.doi.org/10.1107/S1600536814001251
work_keys_str_mv AT mengqingxuan chlorido5methoxy1hbenzimidazole23hthioneksbistriphenylphosphanekpcopperimethanoldisolvate