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[1H-1,2,4-Triazole-5(4H)-thione-κS]bis­(tri­phenyl­phosphane-κP)(nitrato-κO)silver(I) methanol monosolvate

In the title complex, [Ag(NO(3))(C(2)H(3)N(3)S)(C(18)H(15)P)(2)]·CH(3)OH, the Ag(I) ion exhibits a distorted tetra­hedral coordination geometry formed by two P atoms from two tri­phenyl­phosphine ligands, one S atom from a 1H-1,2,4-triazole-5(4H)-thione ligand and one O atom from a nitrate ion. In t...

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Autores principales: Wattanakanjana, Yupa, Palamae, Sureeporn, Ratthiwan, Jenejira, Nimthong, Ruthairat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998265/
https://www.ncbi.nlm.nih.gov/pubmed/24764826
http://dx.doi.org/10.1107/S1600536814001196
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author Wattanakanjana, Yupa
Palamae, Sureeporn
Ratthiwan, Jenejira
Nimthong, Ruthairat
author_facet Wattanakanjana, Yupa
Palamae, Sureeporn
Ratthiwan, Jenejira
Nimthong, Ruthairat
author_sort Wattanakanjana, Yupa
collection PubMed
description In the title complex, [Ag(NO(3))(C(2)H(3)N(3)S)(C(18)H(15)P)(2)]·CH(3)OH, the Ag(I) ion exhibits a distorted tetra­hedral coordination geometry formed by two P atoms from two tri­phenyl­phosphine ligands, one S atom from a 1H-1,2,4-triazole-5(4H)-thione ligand and one O atom from a nitrate ion. In the crystal, complex and solvent mol­ecules are linked by O—H⋯O and N—H⋯O hydrogen bonds forming a chain along the b-axis direction. The chains are linked by weak C—H⋯O hydrogen bonds forming a two-dimensional supra­molecular architecture parallel to (001). In addition, an intra­molecular N—H⋯O hydrogen bond is observed.
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spelling pubmed-39982652014-04-24 [1H-1,2,4-Triazole-5(4H)-thione-κS]bis­(tri­phenyl­phosphane-κP)(nitrato-κO)silver(I) methanol monosolvate Wattanakanjana, Yupa Palamae, Sureeporn Ratthiwan, Jenejira Nimthong, Ruthairat Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ag(NO(3))(C(2)H(3)N(3)S)(C(18)H(15)P)(2)]·CH(3)OH, the Ag(I) ion exhibits a distorted tetra­hedral coordination geometry formed by two P atoms from two tri­phenyl­phosphine ligands, one S atom from a 1H-1,2,4-triazole-5(4H)-thione ligand and one O atom from a nitrate ion. In the crystal, complex and solvent mol­ecules are linked by O—H⋯O and N—H⋯O hydrogen bonds forming a chain along the b-axis direction. The chains are linked by weak C—H⋯O hydrogen bonds forming a two-dimensional supra­molecular architecture parallel to (001). In addition, an intra­molecular N—H⋯O hydrogen bond is observed. International Union of Crystallography 2014-01-22 /pmc/articles/PMC3998265/ /pubmed/24764826 http://dx.doi.org/10.1107/S1600536814001196 Text en © Wattanakanjana et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wattanakanjana, Yupa
Palamae, Sureeporn
Ratthiwan, Jenejira
Nimthong, Ruthairat
[1H-1,2,4-Triazole-5(4H)-thione-κS]bis­(tri­phenyl­phosphane-κP)(nitrato-κO)silver(I) methanol monosolvate
title [1H-1,2,4-Triazole-5(4H)-thione-κS]bis­(tri­phenyl­phosphane-κP)(nitrato-κO)silver(I) methanol monosolvate
title_full [1H-1,2,4-Triazole-5(4H)-thione-κS]bis­(tri­phenyl­phosphane-κP)(nitrato-κO)silver(I) methanol monosolvate
title_fullStr [1H-1,2,4-Triazole-5(4H)-thione-κS]bis­(tri­phenyl­phosphane-κP)(nitrato-κO)silver(I) methanol monosolvate
title_full_unstemmed [1H-1,2,4-Triazole-5(4H)-thione-κS]bis­(tri­phenyl­phosphane-κP)(nitrato-κO)silver(I) methanol monosolvate
title_short [1H-1,2,4-Triazole-5(4H)-thione-κS]bis­(tri­phenyl­phosphane-κP)(nitrato-κO)silver(I) methanol monosolvate
title_sort [1h-1,2,4-triazole-5(4h)-thione-κs]bis­(tri­phenyl­phosphane-κp)(nitrato-κo)silver(i) methanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998265/
https://www.ncbi.nlm.nih.gov/pubmed/24764826
http://dx.doi.org/10.1107/S1600536814001196
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