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[1H-1,2,4-Triazole-5(4H)-thione-κS]bis(triphenylphosphane-κP)(nitrato-κO)silver(I) methanol monosolvate
In the title complex, [Ag(NO(3))(C(2)H(3)N(3)S)(C(18)H(15)P)(2)]·CH(3)OH, the Ag(I) ion exhibits a distorted tetrahedral coordination geometry formed by two P atoms from two triphenylphosphine ligands, one S atom from a 1H-1,2,4-triazole-5(4H)-thione ligand and one O atom from a nitrate ion. In t...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998265/ https://www.ncbi.nlm.nih.gov/pubmed/24764826 http://dx.doi.org/10.1107/S1600536814001196 |
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author | Wattanakanjana, Yupa Palamae, Sureeporn Ratthiwan, Jenejira Nimthong, Ruthairat |
author_facet | Wattanakanjana, Yupa Palamae, Sureeporn Ratthiwan, Jenejira Nimthong, Ruthairat |
author_sort | Wattanakanjana, Yupa |
collection | PubMed |
description | In the title complex, [Ag(NO(3))(C(2)H(3)N(3)S)(C(18)H(15)P)(2)]·CH(3)OH, the Ag(I) ion exhibits a distorted tetrahedral coordination geometry formed by two P atoms from two triphenylphosphine ligands, one S atom from a 1H-1,2,4-triazole-5(4H)-thione ligand and one O atom from a nitrate ion. In the crystal, complex and solvent molecules are linked by O—H⋯O and N—H⋯O hydrogen bonds forming a chain along the b-axis direction. The chains are linked by weak C—H⋯O hydrogen bonds forming a two-dimensional supramolecular architecture parallel to (001). In addition, an intramolecular N—H⋯O hydrogen bond is observed. |
format | Online Article Text |
id | pubmed-3998265 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39982652014-04-24 [1H-1,2,4-Triazole-5(4H)-thione-κS]bis(triphenylphosphane-κP)(nitrato-κO)silver(I) methanol monosolvate Wattanakanjana, Yupa Palamae, Sureeporn Ratthiwan, Jenejira Nimthong, Ruthairat Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ag(NO(3))(C(2)H(3)N(3)S)(C(18)H(15)P)(2)]·CH(3)OH, the Ag(I) ion exhibits a distorted tetrahedral coordination geometry formed by two P atoms from two triphenylphosphine ligands, one S atom from a 1H-1,2,4-triazole-5(4H)-thione ligand and one O atom from a nitrate ion. In the crystal, complex and solvent molecules are linked by O—H⋯O and N—H⋯O hydrogen bonds forming a chain along the b-axis direction. The chains are linked by weak C—H⋯O hydrogen bonds forming a two-dimensional supramolecular architecture parallel to (001). In addition, an intramolecular N—H⋯O hydrogen bond is observed. International Union of Crystallography 2014-01-22 /pmc/articles/PMC3998265/ /pubmed/24764826 http://dx.doi.org/10.1107/S1600536814001196 Text en © Wattanakanjana et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wattanakanjana, Yupa Palamae, Sureeporn Ratthiwan, Jenejira Nimthong, Ruthairat [1H-1,2,4-Triazole-5(4H)-thione-κS]bis(triphenylphosphane-κP)(nitrato-κO)silver(I) methanol monosolvate |
title | [1H-1,2,4-Triazole-5(4H)-thione-κS]bis(triphenylphosphane-κP)(nitrato-κO)silver(I) methanol monosolvate |
title_full | [1H-1,2,4-Triazole-5(4H)-thione-κS]bis(triphenylphosphane-κP)(nitrato-κO)silver(I) methanol monosolvate |
title_fullStr | [1H-1,2,4-Triazole-5(4H)-thione-κS]bis(triphenylphosphane-κP)(nitrato-κO)silver(I) methanol monosolvate |
title_full_unstemmed | [1H-1,2,4-Triazole-5(4H)-thione-κS]bis(triphenylphosphane-κP)(nitrato-κO)silver(I) methanol monosolvate |
title_short | [1H-1,2,4-Triazole-5(4H)-thione-κS]bis(triphenylphosphane-κP)(nitrato-κO)silver(I) methanol monosolvate |
title_sort | [1h-1,2,4-triazole-5(4h)-thione-κs]bis(triphenylphosphane-κp)(nitrato-κo)silver(i) methanol monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998265/ https://www.ncbi.nlm.nih.gov/pubmed/24764826 http://dx.doi.org/10.1107/S1600536814001196 |
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