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Bis(n-do­decyl­ammonium) bis­(chlor­anil­ato)di­ethano­lcuprate(II)

In the title compound, (C(12)H(25)NH(3))(2)[Cu(C(6)Cl(2)O(4))(2)(C(2)H(5)OH)(2)], the Cu(II) atom lies on a crystallographic inversion center and is coordinated in a distorted octa­hedral geometry by four O atoms of two chloranilate ligands and two O atoms of two ethanol mol­ecules which are trans t...

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Detalles Bibliográficos
Autores principales: Himegi, Akiko, Kawata, Satoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998266/
https://www.ncbi.nlm.nih.gov/pubmed/24764827
http://dx.doi.org/10.1107/S1600536814001202
Descripción
Sumario:In the title compound, (C(12)H(25)NH(3))(2)[Cu(C(6)Cl(2)O(4))(2)(C(2)H(5)OH)(2)], the Cu(II) atom lies on a crystallographic inversion center and is coordinated in a distorted octa­hedral geometry by four O atoms of two chloranilate ligands and two O atoms of two ethanol mol­ecules which are trans to each other in the axial positions. In the crystal, the Cu(II) mononuclear dianions are linked by O—H⋯O hydrogen bonds into a tape along the a-axis direction. The tapes are linked through N—H⋯O hydrogen bonds between the dianion and the n-do­decyl­ammonium cation, forming a two-dimensional network parallel to the ab plane.