Bis(n-do­decyl­ammonium) bis­(chlor­anil­ato)di­ethano­lcuprate(II)

In the title compound, (C(12)H(25)NH(3))(2)[Cu(C(6)Cl(2)O(4))(2)(C(2)H(5)OH)(2)], the Cu(II) atom lies on a crystallographic inversion center and is coordinated in a distorted octa­hedral geometry by four O atoms of two chloranilate ligands and two O atoms of two ethanol mol­ecules which are trans t...

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Detalles Bibliográficos
Autores principales: Himegi, Akiko, Kawata, Satoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998266/
https://www.ncbi.nlm.nih.gov/pubmed/24764827
http://dx.doi.org/10.1107/S1600536814001202
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author Himegi, Akiko
Kawata, Satoshi
author_facet Himegi, Akiko
Kawata, Satoshi
author_sort Himegi, Akiko
collection PubMed
description In the title compound, (C(12)H(25)NH(3))(2)[Cu(C(6)Cl(2)O(4))(2)(C(2)H(5)OH)(2)], the Cu(II) atom lies on a crystallographic inversion center and is coordinated in a distorted octa­hedral geometry by four O atoms of two chloranilate ligands and two O atoms of two ethanol mol­ecules which are trans to each other in the axial positions. In the crystal, the Cu(II) mononuclear dianions are linked by O—H⋯O hydrogen bonds into a tape along the a-axis direction. The tapes are linked through N—H⋯O hydrogen bonds between the dianion and the n-do­decyl­ammonium cation, forming a two-dimensional network parallel to the ab plane.
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spelling pubmed-39982662014-04-24 Bis(n-do­decyl­ammonium) bis­(chlor­anil­ato)di­ethano­lcuprate(II) Himegi, Akiko Kawata, Satoshi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(12)H(25)NH(3))(2)[Cu(C(6)Cl(2)O(4))(2)(C(2)H(5)OH)(2)], the Cu(II) atom lies on a crystallographic inversion center and is coordinated in a distorted octa­hedral geometry by four O atoms of two chloranilate ligands and two O atoms of two ethanol mol­ecules which are trans to each other in the axial positions. In the crystal, the Cu(II) mononuclear dianions are linked by O—H⋯O hydrogen bonds into a tape along the a-axis direction. The tapes are linked through N—H⋯O hydrogen bonds between the dianion and the n-do­decyl­ammonium cation, forming a two-dimensional network parallel to the ab plane. International Union of Crystallography 2014-01-22 /pmc/articles/PMC3998266/ /pubmed/24764827 http://dx.doi.org/10.1107/S1600536814001202 Text en © Himegi and Kawata 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Himegi, Akiko
Kawata, Satoshi
Bis(n-do­decyl­ammonium) bis­(chlor­anil­ato)di­ethano­lcuprate(II)
title Bis(n-do­decyl­ammonium) bis­(chlor­anil­ato)di­ethano­lcuprate(II)
title_full Bis(n-do­decyl­ammonium) bis­(chlor­anil­ato)di­ethano­lcuprate(II)
title_fullStr Bis(n-do­decyl­ammonium) bis­(chlor­anil­ato)di­ethano­lcuprate(II)
title_full_unstemmed Bis(n-do­decyl­ammonium) bis­(chlor­anil­ato)di­ethano­lcuprate(II)
title_short Bis(n-do­decyl­ammonium) bis­(chlor­anil­ato)di­ethano­lcuprate(II)
title_sort bis(n-do­decyl­ammonium) bis­(chlor­anil­ato)di­ethano­lcuprate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998266/
https://www.ncbi.nlm.nih.gov/pubmed/24764827
http://dx.doi.org/10.1107/S1600536814001202
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