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Tris(2,6-dibenzoyl-4-methyl­phenolato-κ(2) O (1),O (2))cobalt(III)

In the title compound, [Co(C(21)H(15)O(3))(3)], the Co(III) ion is coordinated in a slightly distorted octa­hedral environment by three phenolate O and three benzoyl O atoms from three monoanionic bidentate 2,6-dibenzoyl-4-methyl­phenolate ligands. The dihedral angles between the mean planes of the...

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Detalles Bibliográficos
Autores principales: Gupta, Abhishek K., Srivastava, Sanjay, Butcher, Ray J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998268/
https://www.ncbi.nlm.nih.gov/pubmed/24764829
http://dx.doi.org/10.1107/S1600536814001664
Descripción
Sumario:In the title compound, [Co(C(21)H(15)O(3))(3)], the Co(III) ion is coordinated in a slightly distorted octa­hedral environment by three phenolate O and three benzoyl O atoms from three monoanionic bidentate 2,6-dibenzoyl-4-methyl­phenolate ligands. The dihedral angles between the mean planes of the central phenolate rings and the peripheral phenyl rings are 46.62 (10)/87.06 (9), 60.44 (8)/23.13 (8) and 46.49 (6)/65.29 (6)°. The crystal packing is stabilized by weak inter­molecular C—H⋯O inter­actions. Mol­ecules are further linked by two π–π [centroid–centroid distances = 3.8612 (14) and 3.9479 (14) Å] and four C—H⋯π inter­actions, forming a three-dimensional network.