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Tris(2,6-dibenzoyl-4-methylphenolato-κ(2) O (1),O (2))cobalt(III)
In the title compound, [Co(C(21)H(15)O(3))(3)], the Co(III) ion is coordinated in a slightly distorted octahedral environment by three phenolate O and three benzoyl O atoms from three monoanionic bidentate 2,6-dibenzoyl-4-methylphenolate ligands. The dihedral angles between the mean planes of the...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998268/ https://www.ncbi.nlm.nih.gov/pubmed/24764829 http://dx.doi.org/10.1107/S1600536814001664 |
Sumario: | In the title compound, [Co(C(21)H(15)O(3))(3)], the Co(III) ion is coordinated in a slightly distorted octahedral environment by three phenolate O and three benzoyl O atoms from three monoanionic bidentate 2,6-dibenzoyl-4-methylphenolate ligands. The dihedral angles between the mean planes of the central phenolate rings and the peripheral phenyl rings are 46.62 (10)/87.06 (9), 60.44 (8)/23.13 (8) and 46.49 (6)/65.29 (6)°. The crystal packing is stabilized by weak intermolecular C—H⋯O interactions. Molecules are further linked by two π–π [centroid–centroid distances = 3.8612 (14) and 3.9479 (14) Å] and four C—H⋯π interactions, forming a three-dimensional network. |
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