Cargando…
Tris(2,6-dibenzoyl-4-methylphenolato-κ(2) O (1),O (2))cobalt(III)
In the title compound, [Co(C(21)H(15)O(3))(3)], the Co(III) ion is coordinated in a slightly distorted octahedral environment by three phenolate O and three benzoyl O atoms from three monoanionic bidentate 2,6-dibenzoyl-4-methylphenolate ligands. The dihedral angles between the mean planes of the...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998268/ https://www.ncbi.nlm.nih.gov/pubmed/24764829 http://dx.doi.org/10.1107/S1600536814001664 |
| _version_ | 1782313324670615552 |
|---|---|
| author | Gupta, Abhishek K. Srivastava, Sanjay Butcher, Ray J. |
| author_facet | Gupta, Abhishek K. Srivastava, Sanjay Butcher, Ray J. |
| author_sort | Gupta, Abhishek K. |
| collection | PubMed |
| description | In the title compound, [Co(C(21)H(15)O(3))(3)], the Co(III) ion is coordinated in a slightly distorted octahedral environment by three phenolate O and three benzoyl O atoms from three monoanionic bidentate 2,6-dibenzoyl-4-methylphenolate ligands. The dihedral angles between the mean planes of the central phenolate rings and the peripheral phenyl rings are 46.62 (10)/87.06 (9), 60.44 (8)/23.13 (8) and 46.49 (6)/65.29 (6)°. The crystal packing is stabilized by weak intermolecular C—H⋯O interactions. Molecules are further linked by two π–π [centroid–centroid distances = 3.8612 (14) and 3.9479 (14) Å] and four C—H⋯π interactions, forming a three-dimensional network. |
| format | Online Article Text |
| id | pubmed-3998268 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-39982682014-04-24 Tris(2,6-dibenzoyl-4-methylphenolato-κ(2) O (1),O (2))cobalt(III) Gupta, Abhishek K. Srivastava, Sanjay Butcher, Ray J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(21)H(15)O(3))(3)], the Co(III) ion is coordinated in a slightly distorted octahedral environment by three phenolate O and three benzoyl O atoms from three monoanionic bidentate 2,6-dibenzoyl-4-methylphenolate ligands. The dihedral angles between the mean planes of the central phenolate rings and the peripheral phenyl rings are 46.62 (10)/87.06 (9), 60.44 (8)/23.13 (8) and 46.49 (6)/65.29 (6)°. The crystal packing is stabilized by weak intermolecular C—H⋯O interactions. Molecules are further linked by two π–π [centroid–centroid distances = 3.8612 (14) and 3.9479 (14) Å] and four C—H⋯π interactions, forming a three-dimensional network. International Union of Crystallography 2014-01-29 /pmc/articles/PMC3998268/ /pubmed/24764829 http://dx.doi.org/10.1107/S1600536814001664 Text en © Gupta et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Gupta, Abhishek K. Srivastava, Sanjay Butcher, Ray J. Tris(2,6-dibenzoyl-4-methylphenolato-κ(2) O (1),O (2))cobalt(III) |
| title | Tris(2,6-dibenzoyl-4-methylphenolato-κ(2)
O
(1),O
(2))cobalt(III) |
| title_full | Tris(2,6-dibenzoyl-4-methylphenolato-κ(2)
O
(1),O
(2))cobalt(III) |
| title_fullStr | Tris(2,6-dibenzoyl-4-methylphenolato-κ(2)
O
(1),O
(2))cobalt(III) |
| title_full_unstemmed | Tris(2,6-dibenzoyl-4-methylphenolato-κ(2)
O
(1),O
(2))cobalt(III) |
| title_short | Tris(2,6-dibenzoyl-4-methylphenolato-κ(2)
O
(1),O
(2))cobalt(III) |
| title_sort | tris(2,6-dibenzoyl-4-methylphenolato-κ(2)
o
(1),o
(2))cobalt(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998268/ https://www.ncbi.nlm.nih.gov/pubmed/24764829 http://dx.doi.org/10.1107/S1600536814001664 |
| work_keys_str_mv | AT guptaabhishekk tris26dibenzoyl4methylphenolatok2o1o2cobaltiii AT srivastavasanjay tris26dibenzoyl4methylphenolatok2o1o2cobaltiii AT butcherrayj tris26dibenzoyl4methylphenolatok2o1o2cobaltiii |